Effect of curve crossing on absorption and resonance Raman spectra: analytical treatment for delta-function coupling in parabolic potentials

被引：15

作者：

Chakraborty, Aniruddha ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

MOLECULAR PHYSICS | 2009年 / 107卷 / 02期

关键词：

ab initio; electronic structure; quantum chemistry; computational chemistry; TRANSITIONS;

D O I：

10.1080/00268970902744342

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose an exactly solvable model for the two-state curve-crossing problem. Our model assumes the coupling to be a delta function. It is used to calculate the effect of curve crossing on the electronic absorption spectrum and the resonance Raman excitation profile.

引用

页码：165 / 169

页数：5

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