Metallo-polymerization/-cyclization of a C16-bridged di-terpyridine ligand and iron(II) ions

被引：20
作者：
Andres, PR
Schubert, US
机构：
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Univ Munich, Ctr Nanosci, D-80333 Munich, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 15期
关键词：
addition polymerization; macrocycles; terpyridine telechelic; transition metal chemistry; viscosity;
D O I：
10.1002/marc.200400177
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The coordinative polymerization/cyclization of a flexible monodisperse di-terpyridine ligand with iron(II) chloride is reported. Matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) investigations showed the preferred formation of a [2 + 2] macrocycle, but also larger aggregates (cycles or linear oligomers) with up to 10 monomer units were found. Because of its C-16-spacer, the solubility is sufficient for performing viscosity experiments in CHCl3/MeOH solution. A viscosity titration revealed a maximum in viscosity at the 1-to-1 ratio of iron(n) ions to di-terpyridine-ligands, which indicates the formation of extended oligomers, polymers, catenanes and/or cycles at that ratio.
引用
收藏
页码：1371 / 1375
页数：5
相关论文
共 32 条
  • [1] Formation of metallo-polymers and -macrocycles by complexation of alkyl-linked di-terpyridines with iron(II) ions
    Andres, PR
    Schubert, US
    [J]. SYNTHESIS-STUTTGART, 2004, (08): : 1229 - 1238
  • [2] Photophysics and redox behavior of chiral transition metal polymers
    Barron, JA
    Glazier, S
    Bernhard, S
    Takada, K
    Houston, PL
    Abruña, HD
    [J]. INORGANIC CHEMISTRY, 2003, 42 (05) : 1448 - 1455
  • [3] Enantiomerically pure chiral coordination polymers:: Synthesis, spectroscopy, and electrochemistry in solution and on surfaces
    Bernhard, S
    Takada, K
    Díaz, DJ
    Abruña, HD
    Mürner, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) : 10265 - 10271
  • [4] Supramolecular polymers
    Brunsveld, L
    Folmer, BJB
    Meijer, EW
    Sijbesma, RP
    [J]. CHEMICAL REVIEWS, 2001, 101 (12) : 4071 - 4097
  • [5] Metal-directed assembly of a conformationally restricted metallomacrocycle
    Chow, HS
    Constable, EC
    Housecroft, CE
    Neuburger, M
    [J]. DALTON TRANSACTIONS, 2003, Royal Society of Chemistry (24) : 4568 - 4569
  • [6] Self-assembly of two discrete polynuclear iron(II) metallomacrocycles from a ligand containing two 2,2′:6′, 2"-terpyridine binding domains
    Constable, EC
    Housecroft, CE
    Smith, CB
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (08) : 1011 - 1013
  • [7] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES
    CONSTABLE, EC
    [J]. ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 : 69 - 121
  • [8] Synthesis of π-conjugated oligomer that can form metallo polymers
    El-Ghayoury, A
    Schenning, APHJ
    Meijer, EW
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (22) : 4020 - 4023
  • [9] Heller M, 2002, E-POLYMERS
  • [10] Heller M, 2002, MACROMOL SYMP, V177, P87, DOI 10.1002/1521-3900(200201)177:1<87::AID-MASY87>3.0.CO
1234