Measurement of the viscosity of binary and ternary systems containing benzaldehyde, toluene, and benzyl alcohol at 293.15 K and 0.1 MPa

被引:9
作者
Cruz, RD
Martins, RJ
Cardoso, MJED
Barcia, OE
机构
[1] Univ Fed Rio de Janeiro, Lab Fisicoquim Liquidos & Eletroquim, Dept Fisicoquim, Inst Quim,Ctr Tecnol, BR-21949900 Rio De Janeiro, Brazil
[2] Univ Fed Fluminense, Dept Fisicoquim, Inst Quim, BR-24020150 Niteroi, RJ, Brazil
关键词
D O I
10.1021/je010327v
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this work we measure the density and viscosity of the ternary system benzyl alcohol (1) + benzaldehyde (2) + toluene (3) at 293.15 K and 0.1 MPa for 21 different ternary composition sets. Values of the viscosity and density of the respective binary systems, over the whole composition range at the same temperature and pressure conditions, are also presented. Experimental data of binary systems were used to determine the excess molar volumes and the viscosity deviations which were fitted by means of Redlich-Kister polynomials. The experimental data of the dynamic viscosity of the binary systems have been used to obtain the binary interaction parameters of a model recently proposed in the literature by our group. The overall mean relative standard deviation between experimental and calculated viscosities for the ternary system was 1.1%.
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页码:927 / 931
页数:5
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