Facile synthesis of boron and nitrogen-doped graphene as efficient electrocatalyst for the oxygen reduction reaction in alkaline media

被引：136

作者：

Xu, Xiao ^{[1
]}

Yuan, Tao ^{[1
]}

Zhou, Yingke ^{[1
]}

Li, Yawei ^{[1
]}

Lu, Jiming ^{[1
]}

Tian, Xiaohui ^{[1
]}

Wang, Deli ^{[2
]}

Wang, Jie ^{[2
]}

机构：

[1] Wuhan Univ Sci & Technol, Coll Mat & Met, State Key Lab Breeding Base Refractories & Ceram, Wuhan 430081, Peoples R China

[2] Huazhong Univ Sci & Technol, Minist Educ, Key Lab Large Format Battery Mat & Syst, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 28期

基金：

中国国家自然科学基金;

关键词：

Graphene; Boron doping; Nitrogen doping; Oxygen reduction reaction; METAL-FREE CATALYST; CARBON; OXIDE; METHANOL;

D O I：

10.1016/j.ijhydene.2013.12.079

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Boron-doped graphene and nitrogen-doped graphene have been respectively synthesized by a facile thermal solid-state reaction of graphene oxide with boric acid and urea. The morphology and structure of the doped graphene have been characterized by the scanning electron microscopy, infrared spectroscopy, ultraviolet visible spectroscopy and X-ray photoelectron spectroscopy, while the electrocatalytic activity toward oxygen reduction reaction has been evaluated by the cyclic voltammetry. It has been shown that the morphology, structure, doping level and fashions of graphene could be finely tuned by the thermal treatment conditions, and which have substantial effects on the activity of oxygen reduction reaction. The boron-doped graphene and nitrogen-doped graphene calcined at 700 degrees C demonstrate excellent electrocatalytic oxygen reduction activities as the appropriate introduction of boron and nitrogen functional groups in graphene, which might be promising for low temperature fuel cell applications. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：16043 / 16052

页数：10

共 39 条

[11] Facile preparation of nitrogen-doped graphene as a metal-free catalyst for oxygen reduction reaction [J].

Lin, Ziyin ;

Song, Min-kyu ;

Ding, Yong ;

Liu, Yan ;

Liu, Meilin ;

Wong, Ching-ping .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (10) :3381-3387

[12] Synthesis of boron-doped double-walled carbon nanotubes by the catalytic decomposition of tetrahydrofuran and triisopropyl borate [J].

Lyu, S. C. ;

Han, J. H. ;

Shin, K. W. ;

Sok, J. H. .

CARBON, 2011, 49 (05) :1532-1541

[13] Nitrogen-doped graphene prepared by a transfer doping approach for the oxygen reduction reaction application [J].

Mo, Zaiyong ;

Zheng, Ruiping ;

Peng, Hongliang ;

Liang, Huagen ;

Liao, Shijun .

JOURNAL OF POWER SOURCES, 2014, 245 :801-807

[14] Forming mechanism of nitrogen doped graphene prepared by thermal solid-state reaction of graphite oxide and urea [J].

Mou, Zhigang ;

Chen, Xiaoye ;

Du, Yukou ;

Wang, Xiaomei ;

Yang, Ping ;

Wang, Suidong .

APPLIED SURFACE SCIENCE, 2011, 258 (05) :1704-1710

[15] Pyrolytic synthesis of boron-doped graphene and its application as electrode material for supercapacitors [J].

Niu, Lengyuan ;

Li, Zhangpeng ;

Hong, Wei ;

Sun, Jinfeng ;

Wang, Zhaofeng ;

Ma, Limin ;

Wang, Jinqing ;

Yang, Shengrong .

ELECTROCHIMICA ACTA, 2013, 108 :666-673

[16] Synthesis, Structure, and Properties of Boron- and Nitrogen-Doped Graphene [J].

Panchokarla, L. S. ;

Subrahmanyam, K. S. ;

Saha, S. K. ;

Govindaraj, Achutharao ;

Krishnamurthy, H. R. ;

Waghmare, U. V. ;

Rao, C. N. R. .

ADVANCED MATERIALS, 2009, 21 (46) :4726-+

[17] XPS study and physico-chemical properties of nitrogen-enriched microporous activated carbon from high volatile bituminous coal [J].

Pietrzak, Robert .

FUEL, 2009, 88 (10) :1871-1877

[18] Oxygen dissociation on nitrogen-doped single wall nanotube: A first-principles study [J].

Shan, Bin ;

Cho, Kyeongjae .

CHEMICAL PHYSICS LETTERS, 2010, 492 (1-3) :131-136

[19] INFRARED STUDY OF AMORPHOUS B1-XCX FILMS [J].

SHIRAI, K ;

EMURA, S ;

GONDA, SI ;

KUMASHIRO, Y .

JOURNAL OF APPLIED PHYSICS, 1995, 78 (05) :3392-3400

[20] Synthesis and characterization of a nanocomposite of goethite nanorods and reduced graphene oxide for electrochemical capacitors [J].

Shou, Qingliang ;

Cheng, Jipeng ;

Zhang, Li ;

Nelson, Bradley J. ;

Zhang, Xiaobin .

JOURNAL OF SOLID STATE CHEMISTRY, 2012, 185 :191-197

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