Copper-nickel-modified Boron-doped Diamond Electrode for CO2 Electrochemical Reduction Application: A Preliminary Study

被引：16

作者：

Jiwanti, Prastika Krisma ^{[1
,3
]}

Aritonang, Rani Puspitasari ^{[2
]}

Abdullah, Imam ^{[2
]}

Einaga, Yasuaki ^{[3
]}

Ivandini, Tribidasari Anggraningrum ^{[2
]}

机构：

[1] Univ Airlangga, Fac Sci & Technol, Dept Chem, Surabaya 60115, Indonesia

[2] Univ Indonesia, Fac Math & Nat Sci, Dept Chem, Depok 16424, Indonesia

[3] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan

来源：

MAKARA JOURNAL OF SCIENCE | 2019年 / 23卷 / 04期

关键词：

boron-doped diamond; CO2; reduction; copper-nickel; CARBON-DIOXIDE; FORMIC-ACID; METHANE; ELECTROREDUCTION; SELECTIVITY;

D O I：

10.7454/mss.v23i4.11512

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

CO2 electrochemical reduction (CO2ER) activity is known to be influenced by electrode materials. In this study, we report the fabrication of a copper-nickel-modified boron-doped diamond (CuNi-BDD) electrode using wet chemical seeding and electrodeposition. Annealing was performed to improve the stability of the modified electrode during electrolysis. Characterization of the modified BDD electrodes shows successful deposition without damage to the surface of the BDD support material. CO2ER was conducted with the CuNi-BDD electrode, which produces various important products including methanol, formic acid, CO, and CH4. Additionally, a different applied potential affected the product distribution. CO2ER was also conducted on the surfaces of Cu-BDD and Ni-BDD electrodes for comparison.

引用

页码：204 / 209

页数：6

共 22 条

[1] Highly stable platinum nanoparticles on diamond [J].

Gao, Fang ;

Yang, Nianjun ;

Nebel, Christoph E. .

ELECTROCHIMICA ACTA, 2013, 112 :493-499

[2] CO2 Electrochemical Reduction to Methane and Methanol on Copper-Based Alloys: Theoretical Insight [J].

Hirunsit, Pussana ;

Soodsawang, Wiwaporn ;

Limtrakul, Jumras .

JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (15) :8238-8249

[3] ELECTROCATALYTIC PROCESS OF CO SELECTIVITY IN ELECTROCHEMICAL REDUCTION OF CO2 AT METAL-ELECTRODES IN AQUEOUS-MEDIA [J].

HORI, Y ;

WAKEBE, H ;

TSUKAMOTO, T ;

KOGA, O .

ELECTROCHIMICA ACTA, 1994, 39 (11-12) :1833-1839

[4] Effect of alkali-metal cations on the electrochemical reduction of carbon dioxide to formic acid using boron-doped diamond electrodes [J].

Ikemiya, Norihito ;

Natsui, Keisuke ;

Nakata, Kazuya ;

Einaga, Yasuaki .

RSC ADVANCES, 2017, 7 (36) :22510-22514

[5] Polycrystalline boron-doped diamond electrodes for electrocatalytic and electrosynthetic applications [J].

Ivandini, Tribidasari A. ;

Einaga, Yasuaki .

CHEMICAL COMMUNICATIONS, 2017, 53 (08) :1338-1347

[6] The electrochemical production of C2/C3 species from carbon dioxide on copper-modified boron-doped diamond electrodes [J].

Jiwanti, Prastika K. ;

Natsui, Keisuke ;

Nakata, Kazuya ;

Einaga, Yasuaki .

ELECTROCHIMICA ACTA, 2018, 266 :414-419

[7] Selective production of methanol by the electrochemical reduction of CO2 on boron-doped diamond electrodes in aqueous ammonia solution [J].

Jiwanti, Prastika K. ;

Natsui, Keisuke ;

Nakata, Kazuya ;

Einaga, Yasuaki .

RSC ADVANCES, 2016, 6 (104) :102214-102217

[8]

Kaneco S., 2007, B CATALSOC INDIA, V6, P74

[9] Copper nanoparticle ensembles for selective electroreduction of CO2 to C2-C3 products [J].

Kim, Dohyung ;

Kley, Christopher S. ;

Li, Yifan ;

Yang, Peidong .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (40) :10560-10565

[10] Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces [J].

Kuhl, Kendra P. ;

Hatsukade, Toru ;

Cave, Etosha R. ;

Abram, David N. ;

Kibsgaard, Jakob ;

Jaramillo, Thomas F. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (40) :14107-14113

← 1 2 3 →