Gating Charge Recombination Rates through Dynamic Bridges in Tetrathiafulvalene-Fullerene Architectures

被引：37

作者：

Castellanos, Sonia ^{[1
]}

Vieira, Andre A. ^{[2
]}

Illescas, Beatriz M. ^{[2
]}

Sacchetti, Valentina ^{[2
]}

Schubert, Christina ^{[3
]}

Moreno, Javier ^{[1
]}

Guldi, Dirk M. ^{[3
]}

Hecht, Stefan ^{[1
]}

Martin, Nazario ^{[2
]}

机构：

[1] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany

[2] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 52期

基金：

欧洲研究理事会;

关键词：

charge separated state; cyclic voltammetry; electron transfer; photochromism; transient absorption; PHOTOINDUCED ELECTRON-TRANSFER; PORPHYRIN; C-60; DERIVATIVES; MEMORIES; CATION; DYADS; ION;

D O I：

10.1002/anie.201306183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An open and shut case: The competition between charge separation and recombination in artificial photosynthetic systems can be controlled by using photochromic dynamic bridge. The photoinduced opening and closing of the bridge mediates the electronic coupling between donor (D) and acceptor (A). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：13985 / 13990

页数：6

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