A zeolite CAN-type aluminoborate with gigantic 24-ring channels

被引：46

作者：

Cao, Gao-Juan ^{[1
,4
]}

Wei, Qi ^{[1
]}

Cheng, Jian-Wen ^{[2
]}

Cheng, Lin ^{[3
]}

Yang, Guo-Yu ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China

[2] Zhejiang Normal Univ, Inst Phys Chem, Minist Educ Adv Catalysis Mat, Key Lab, Jinhua 321004, Zhejiang, Peoples R China

[3] Tianjin Normal Univ, Sch Chem, Tianjin 300387, Peoples R China

[4] Fujian Agr & Forestry Univ, Sch Life Sci, Dept Appl Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 08期

关键词：

OPEN-FRAMEWORK; PHOSPHITE; GERMANATE; DESIGN; CHEMISTRY; CHLORIDE; CRYSTAL;

D O I：

10.1039/c5cc08164e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cancrinite type aluminoborate with gigantic 24-ring channels has been made under solvothermal conditions using Al(i-PrO)(3) as the Al source and amines as the structure directing agents. Its framework is alternately constructed from B5O10 clusters and AlO4 units, no Al-O-Al linkages exist in the structure. Notably, the wall of the 24-ring channels has odd 11-ring windows, resulting in an unprecedented 3D intersecting channel system.

引用

页码：1729 / 1732

页数：4

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