Three-dimensional imaging of carbonyl sulfide and ethyl iodide photodissociation using the pixel imaging mass spectrometry camera

被引：30

作者：

Amini, K. ^{[1
]}

Blake, S. ^{[1
]}

Brouard, M. ^{[1
]}

Burt, M. B. ^{[1
]}

Halford, E. ^{[1
]}

Lauer, A. ^{[1
]}

Slater, C. S. ^{[1
]}

Lee, J. W. L. ^{[2
]}

Vallance, C. ^{[2
]}

机构：

[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 2015年 / 86卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

TO-STATE PHOTODISSOCIATION; NONADIABATIC BENDING DISSOCIATION; POSITION-SENSITIVE DETECTOR; MICROCHANNEL-PLATE DETECTOR; ABSORPTION CROSS-SECTIONS; TIME-OF-FLIGHT; OCS MONOMERS; VELOCITY; FRAGMENTATION; DYNAMICS;

D O I：

10.1063/1.4934544

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The Pixel Imaging Mass Spectrometry (PImMS) camera is used in proof-of-principle three-dimensional imaging experiments on the photodissociation of carbonyl sulfide and ethyl iodide at wavelengths around 230 nm and 245 nm, respectively. Coupling the PImMS camera with DC-sliced velocity-map imaging allows the complete three-dimensional Newton sphere of photofragment ions to be recorded on each laser pump-probe cycle with a timing precision of 12.5 ns, yielding velocity resolutions along the time-of-flight axis of around 6%-9% in the applications presented. (C) 2015 AIP Publishing LLC.

引用

页数：15

共 84 条

[1] Multi-hit detector system for complete momentum balance in spectroscopy in molecular fragmentation processes [J].

Ali, I ;

Dörner, R ;

Jagutzki, O ;

Nüttgens, S ;

Mergel, V ;

Spielberger, L ;

Khayyat, K ;

Vogt, T ;

Bräuning, H ;

Ullmann, K ;

Moshammer, R ;

Ullrich, J ;

Hagmann, S ;

Groeneveld, KO ;

Cocke, CL ;

Schmidt-Böcking, H .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 149 (04) :490-500

[2] Imaging the dynamics of gas phase reactions [J].

Ashfold, MNR ;

Nahler, NH ;

Orr-Ewing, AJ ;

Vieuxmaire, OPJ ;

Toomes, RL ;

Kitsopoulos, TN ;

Garcia, IA ;

Chestakov, DA ;

Wu, SM ;

Parker, DH .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (01) :26-53

[3] Fourier moment analysis of velocity-map ion images [J].

Bass, MJ ;

Brouard, M ;

Clark, AP ;

Vallance, C .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (19) :8723-8735

[4] The application of the fast, multi-hit, pixel imaging mass spectrometry sensor to spatial imaging mass spectrometry [J].

Brouard, M. ;

Halford, E. ;

Lauer, A. ;

Slater, C. S. ;

Winter, B. ;

Yuen, W. H. ;

John, J. J. ;

Hill, L. ;

Nomerotski, A. ;

Clark, A. ;

Crooks, J. ;

Sedgwick, I. ;

Turchetta, R. ;

Lee, J. W. L. ;

Vallance, C. ;

Wilman, E. .

REVIEW OF SCIENTIFIC INSTRUMENTS, 2012, 83 (11)

[5] The photodissociation dynamics of OCS at 248 nm:: The S(3PJ) atomic angular momentum polarization [J].

Brouard, M. ;

Quadrini, F. ;

Vallance, C. .

JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (08)

[6] Photodissociation dynamics of OCS at 248 nm:: The S(1D2) atomic angular momentum polarization [J].

Brouard, M. ;

Green, A. V. ;

Quadrini, F. ;

Vallance, C. .

JOURNAL OF CHEMICAL PHYSICS, 2007, 127 (08)

[7] Velocity map imaging in time of flight mass spectrometry [J].

Brouard, M. ;

Campbell, E. K. ;

Johnsen, A. J. ;

Vallance, C. ;

Yuen, W. H. ;

Nomerotski, A. .

REVIEW OF SCIENTIFIC INSTRUMENTS, 2008, 79 (12)

[8] AN ALGORITHM FOR THE FOURIER-BESSEL TRANSFORM [J].

CANDEL, SM .

COMPUTER PHYSICS COMMUNICATIONS, 1981, 23 (04) :343-353

[9] TWO-DIMENSIONAL IMAGING OF STATE-SELECTED PHOTODISSOCIATION PRODUCTS DETECTED BY MULTIPHOTON IONIZATION [J].

CHANDLER, DW ;

HOUSTON, PL .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (02) :1445-1447

[10] Improved two-dimensional product imaging: The real-time ion-counting method [J].

Chang, BY ;

Hoetzlein, RC ;

Mueller, JA ;

Geiser, JD ;

Houston, PL .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1998, 69 (04) :1665-1670

← 1 2 3 4 5 6 7 8 9 →