共 33 条
An evaluation of alkylthiols and dialkyl disulfides on deactivation of Cu/Zn catalyst in hydrogenation of dodecyl methyl ester to dodecanol
被引:14
作者:

Huang, Hui
论文数: 0 引用数: 0
h-index: 0
机构:
Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
E China Univ Sci & Technol, State Key Lab Chem Engn, UNILAB, Shanghai 200237, Peoples R China Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China

Cao, Guiping
论文数: 0 引用数: 0
h-index: 0
机构:
E China Univ Sci & Technol, State Key Lab Chem Engn, UNILAB, Shanghai 200237, Peoples R China Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China

Wang, Shaohong
论文数: 0 引用数: 0
h-index: 0
机构:
Shanghai Huayi Grp Co Ltd, Shanghai 200431, Peoples R China Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
机构:
[1] Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
[2] E China Univ Sci & Technol, State Key Lab Chem Engn, UNILAB, Shanghai 200237, Peoples R China
[3] Shanghai Huayi Grp Co Ltd, Shanghai 200431, Peoples R China
关键词:
Fatty alcohol;
Cu/Zn catalyst;
Deactivation;
Sulfur;
RAY PHOTOELECTRON-SPECTROSCOPY;
COPPER METAL-CATALYSTS;
FATTY ALCOHOL;
METHANOL SYNTHESIS;
HYDROGENOLYSIS;
XPS;
D O I:
10.1016/j.jiec.2013.06.033
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Deactivation of co-precipitated Cu/Zn catalyst caused by exposure to either alkylthiols or dialkyl disulfides in catalytic hydrogenation of dodecyl methyl ester to dodecanol is explored in a stirred batch reactor. Catalytic activity decrement is highly dependent on levels of poisons, types of thiols/disulfides, chain length of alkanes. XRD, EDS and XPS are employed to characterize the fresh and spent Cu/Zn catalysts. It is evident that sulfuric species prefer to attack zinc oxide, forming chemically adsorbed Zn-SR at low sulfur levels, and ZnS is formed in the highly reductive atmosphere before sulfuric species attacking copper (forming Cu7S4 or Cu31S16). (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:988 / 993
页数:6
相关论文
共 33 条
[1]
Mechanisms of catalyst deactivation
[J].
Bartholomew, CH
.
APPLIED CATALYSIS A-GENERAL,
2001, 212 (1-2)
:17-60

Bartholomew, CH
论文数: 0 引用数: 0
h-index: 0
机构:
Brigham Young Univ, Dept Chem Engn, Provo, UT 84602 USA Brigham Young Univ, Dept Chem Engn, Provo, UT 84602 USA
[2]
SULFUR POISONING OF METALS
[J].
BARTHOLOMEW, CH
;
AGRAWAL, PK
;
KATZER, JR
.
ADVANCES IN CATALYSIS,
1982, 31
:135-242

BARTHOLOMEW, CH
论文数: 0 引用数: 0
h-index: 0
机构: GEORGIA INST TECHNOL, SCH CHEM ENGN, ATLANTA, GA 30332 USA

AGRAWAL, PK
论文数: 0 引用数: 0
h-index: 0
机构: GEORGIA INST TECHNOL, SCH CHEM ENGN, ATLANTA, GA 30332 USA

KATZER, JR
论文数: 0 引用数: 0
h-index: 0
机构: GEORGIA INST TECHNOL, SCH CHEM ENGN, ATLANTA, GA 30332 USA
[3]
Steam reforming and graphite formation on Ni catalysts
[J].
Bengaard, HS
;
Norskov, JK
;
Sehested, J
;
Clausen, BS
;
Nielsen, LP
;
Molenbroek, AM
;
Rostrup-Nielsen, JR
.
JOURNAL OF CATALYSIS,
2002, 209 (02)
:365-384

Bengaard, HS
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Norskov, JK
论文数: 0 引用数: 0
h-index: 0
机构:
Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Sehested, J
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Clausen, BS
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Nielsen, LP
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Molenbroek, AM
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark

Rostrup-Nielsen, JR
论文数: 0 引用数: 0
h-index: 0
机构: Tech Univ Denmark, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark
[4]
Sulfur deactivation of fatty ester hydrogenolysis catalysts
[J].
Brands, DS
;
U-A-Sai, G
;
Poels, EK
;
Bliek, A
.
JOURNAL OF CATALYSIS,
1999, 186 (01)
:169-180

Brands, DS
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

U-A-Sai, G
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

Poels, EK
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

Bliek, A
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands
[5]
The relation between reduction temperature and activity in copper catalysed ester hydrogenolysis and methanol synthesis
[J].
Brands, DS
;
Poels, EK
;
Krieger, TA
;
Makarova, OV
;
Weber, C
;
Veer, S
;
Bliek, A
.
CATALYSIS LETTERS,
1996, 36 (3-4)
:175-181

Brands, DS
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Poels, EK
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Krieger, TA
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Makarova, OV
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Weber, C
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Veer, S
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS

Bliek, A
论文数: 0 引用数: 0
h-index: 0
机构: UNIV AMSTERDAM,DEPT CHEM ENGN,1018 WV AMSTERDAM,NETHERLANDS
[6]
Ester hydrogenolysis over promoted Cu/SiO2 catalysts
[J].
Brands, DS
;
Poels, EK
;
Bliek, A
.
APPLIED CATALYSIS A-GENERAL,
1999, 184 (02)
:279-289

Brands, DS
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

Poels, EK
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands

Bliek, A
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands Univ Amsterdam, Dept Chem Engn, NL-1018 WV Amsterdam, Netherlands
[7]
Cu-B2O3/SiO2, an effective catalyst for synthesis of fatty alcohol from hydrogenolysis of fatty acid esters
[J].
Chen, YZ
;
Chang, CL
.
CATALYSIS LETTERS,
1997, 48 (1-2)
:101-104

Chen, YZ
论文数: 0 引用数: 0
h-index: 0

Chang, CL
论文数: 0 引用数: 0
h-index: 0
[8]
The development of nonchromium catalyst for fatty alcohol production
[J].
Hattori, Y
;
Yamamoto, K
;
Kaita, J
;
Matsuda, M
;
Yamada, S
.
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY,
2000, 77 (12)
:1283-1287

Hattori, Y
论文数: 0 引用数: 0
h-index: 0
机构: Kao Corp, Mat Dev Res Labs, Wakayama 6408580, Japan

Yamamoto, K
论文数: 0 引用数: 0
h-index: 0
机构: Kao Corp, Mat Dev Res Labs, Wakayama 6408580, Japan

Kaita, J
论文数: 0 引用数: 0
h-index: 0
机构: Kao Corp, Mat Dev Res Labs, Wakayama 6408580, Japan

Matsuda, M
论文数: 0 引用数: 0
h-index: 0
机构: Kao Corp, Mat Dev Res Labs, Wakayama 6408580, Japan

Yamada, S
论文数: 0 引用数: 0
h-index: 0
机构: Kao Corp, Mat Dev Res Labs, Wakayama 6408580, Japan
[9]
Effect of structure of CuO/ZnO/Al2O3 composites on catalytic performance for hydrogenation of fatty acid ester
[J].
He, Limin
;
Cheng, Haiyang
;
Liang, Guanfeng
;
Yu, Yancun
;
Zhao, Fengyu
.
APPLIED CATALYSIS A-GENERAL,
2013, 452
:88-93

He, Limin
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China

Cheng, Haiyang
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China

Liang, Guanfeng
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China

Yu, Yancun
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China

Zhao, Fengyu
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[10]
Diatomite-supported Pd-M (M = Cu, Co, Ni) bimetal nanocatalysts for selective hydrogenation of long-chain aliphatic esters
[J].
Huang, Changliang
;
Zhang, Hongye
;
Zhao, Yanfei
;
Chen, Sha
;
Liu, Zhimin
.
JOURNAL OF COLLOID AND INTERFACE SCIENCE,
2012, 386
:60-65

Huang, Changliang
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

Zhang, Hongye
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

Zhao, Yanfei
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

Chen, Sha
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

Liu, Zhimin
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China