Domino ring opening-ring closing metathesis (ROM-RCM) strategy toward bicyclo[n.3.0]cycloalkenes

被引：43
作者：
Hagiwara, H
Katsumi, T
Endou, S
Hoshi, T
Suzuki, T
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[2] Niigata Univ, Fac Engn, Niigata 9502181, Japan
来源：
TETRAHEDRON | 2002年 / 58卷 / 33期
关键词：
bicyclic aliphatic compounds; metathesis; ring transformations; ruthenium and compounds;
D O I：
10.1016/S0040-4020(02)00690-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of bicyclo[2.2.1]heptene having an exo- or endo-olefinic side chain with a catalytic amount of Grubbs' Ru carbene complex under ethylene atmosphere provided bicyclo[3.3.0]octene or bicyclo[4.3.0]nonene compounds by domino ROM-RCM reaction. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6651 / 6654
页数：4
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