Formation and reactions of a thioxoborane, a novel boron-sulfur double-bond compound

被引：17

作者：

Tokitoh, N

Ito, M

Okazaki, R

机构：

[1] Department of Chemistry, Graduate School of Science, University of Tokyo, Tokyo 113, 7-3-1 Hongo, Bunkyo-ku

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 29期

关键词：

D O I：

10.1016/0040-4039(96)01039-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermolysis of an overcrowded tin-containing four-membered boracycle, 1,3,2-dithiastannaboretane derivative 6, bearing an extremely bulky aryl group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt), on the boron atom in the presence of several 1,3-dienes in toluene at 120 degrees C gave the corresponding diene adducts of an initially formed thioxoborane (Tbt-B=S; 7) together with a trimer of diphenylstannanethione 8. Retro [4+2]cycloaddition of the diene adducts into the thioxoborane 7 is also described. Copyright (C) 1996 Elsevier Science Ltd

引用

收藏

页码：5145 / 5148

页数：4

相关论文

共 13 条

[1] SYNTHESIS AND CHARACTERIZATION OF TRIARYLBORTHIINS, AR3B3S3 (AR = 4-MEC6H4, 3-MEC6H4, 2-MEC6H4, 4-ETC6H4, AND 3,5-ME2C6H3) [J].

BECKETT, MA ;

MINTON, PR ;

WERSCHKUN, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) :37-41

[2]

DUSS F, 1979, COMPREHENSIVE ORGANI, V3, P373

[3] CONTRIBUTIONS TO THE CHEMISTRY OF BORON .171. CRYSTAL AND MOLECULAR-STRUCTURE OF 2,4-BIS(2,2,6,6-TETRAMETHYLPIPERIDINO)-1,3,2,4-DICHALCOGENDIBORETANES [J].

HANECKER, E ;

NOTH, H ;

WIETELMANN, U .

CHEMISCHE BERICHTE-RECUEIL, 1986, 119 (06) :1904-1910

[4] THE MICROWAVE-SPECTRUM OF THE TRANSIENT MOLECULE CHLORO(SULFIDO)BORON, CIB=S - SUBSTITUTION STRUCTURE, DIPOLE-MOMENT, QUADRUPOLE-MOMENT, AND VIBRATION-ROTATION ANALYSIS [J].

KIRBY, C ;

KROTO, HW .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1980, 83 (01) :130-147

[5] DETECTION OF NEW REACTIVE MOLECULE METHYL(SULPHIDO)BORON, MEBS, BY MICROWAVE SPECTROSCOPY [J].

KIRBY, C ;

KROTO, HW ;

TAYLOR, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (01) :19-20

[6] THE MICROWAVE-SPECTRUM OF THE TRANSIENT MOLECULE METHYL SULFIDO BORON, CH3B=S - SUBSTITUTION STRUCTURE, DIPOLE-MOMENT, QUADRUPOLE-MOMENT, AND VIBRATION-ROTATION ANALYSIS [J].

KIRBY, C ;

KROTO, HW .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1980, 83 (01) :1-14

[7]

Kirk R. W., 1967, J CHEM SOC CHEM COMM, P18

[8] SEMISTABLE MOLECULES IN THE LABORATORY AND IN SPACE [J].

KROTO, HW .

CHEMICAL SOCIETY REVIEWS, 1982, 11 (04) :435-491

[9] CONTRIBUTIONS TO THE CHEMISTRY OF BORON .159. [2+2] CYCLO-ADDITIONS OF (TERT-BUTYLIMINO)(2,2,6,6-TETRAMETHYLPIPERIDINO)BORANE WITH CARBON DICHALCOGENIDES [J].

MANNIG, D ;

NARULA, CK ;

NOTH, H ;

WIETELMANN, U .

CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (09) :3748-3758

[10] THE FIRST GENUINE SILICON-SULFUR DOUBLE-BOND COMPOUND - SYNTHESIS AND CRYSTAL-STRUCTURE OF A KINETICALLY STABILIZED SILANETHIONE [J].

SUZUKI, H ;

TOKITOH, N ;

NAGASE, S ;

OKAZAKI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (25) :11578-11579