Strengthened graphene oxide/diazoresin multilayer composites from layer-by-layer assembly and cross-linking

被引:10
作者
Huang, Xian-He [1 ]
Zhang, Meng-Meng [1 ]
Dou, Xin-Wei [1 ]
Lu, Xuan [1 ]
Qin, Yu-Jun [1 ]
Zhang, Pu [1 ]
Shi, Jia-Hua [2 ]
Guo, Zhi-Xin [1 ]
机构
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
[2] Henan Univ, Inst Fine Chem & Engn, Key Lab Nat Med & Immunoengn Henan Prov, Kaifeng 475004, Peoples R China
关键词
Graphene oxide; Diazoresin; Layer-by-layer assembly; Cross-linking; CARBON NANOTUBES; HOLLOW CAPSULES; FILMS; NANOPLATELETS; NANOSHEETS;
D O I
10.1016/j.cclet.2015.04.005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The layer-by-layer assembly of graphene oxide and diazoresin is carried out via the electrostatic and hydrogen bond interactions on planar substrates and colloidal templates. The successful planar and spherical growth of multilayer could be investigated by UV-vis spectrophotometry and scanning electron microscopy, respectively. Subsequent UV irradiation or heating would convert the ionic bonds and hydrogen bonds to covalent bands, which significantly improves the stability of the multilayer composite against solvent etching. For the cross-linked core-shell composites, the template cores could be removed by dissolution and hollow microspheres are obtained. (C) 2015 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1155 / 1157
页数:3
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