Effects of alloyed Si on the autoclave corrosion performance and periodic corrosion kinetics in Zr-Sn-Nb-Fe-O alloys

被引:54
作者
Chen, Liangyu [1 ,4 ]
Li, Jiuxiao [1 ]
Zhang, Yao [1 ]
Zhang, Lai-Chang [2 ]
Lu, Weijie [1 ]
Zhang, Lefu [3 ]
Wang, Liqiang [1 ]
Zhang, Di [1 ]
机构
[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[2] Edith Cowan Univ, Sch Engn, Perth, WA 6027, Australia
[3] Shanghai Jiao Tong Univ, Sch Nucl Sci & Engn, Shanghai 200240, Peoples R China
[4] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Jiangsu, Peoples R China
基金
美国国家科学基金会;
关键词
Zirconium; SEM; TEM; XRD; High temperature corrosion; Oxidation; METAL/OXIDE INTERFACE; MECHANICAL-BEHAVIOR; ZIRCONIUM ALLOYS; OXIDATION; MICROSTRUCTURE; RESISTANCE;
D O I
10.1016/j.corsci.2015.08.043
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper investigates the effect of alloyed Si on the autoclave corrosion performance and corrosion mechanisms of Zr-Sn-Nb-Fe-O alloys. Quantitative analyses are performed on the microstructure of alloys and their oxide behavior. The Si-containing alloy possesses improved corrosion resistance. The reason is that a trace of Si enhances the strength of alloy and thus slows the evolution of undulated interface of oxide/metal which is associated with the formation of cracks in the oxide. The generation of cracks is discussed in further detail in relation to corrosion kinetics. This work advances the understanding of improving the corrosion resistance of zirconium alloys. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:651 / 662
页数:12
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