Ethane Conversion Involving Lattice Oxygen of Oxide Systems

被引：19
|
作者：
Khadzhiev, S. N. [1 ]
Usachev, N. Ya. [2 ]
Gerzeliev, I. M. [1 ]
Kalinin, V. P. [2 ]
Kharlamov, V. V. [2 ]
Belanova, E. P. [2 ]
Kazakov, A. V. [2 ]
Kanaev, S. A. [2 ]
Starostina, T. S. [2 ]
机构：
[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia
[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
来源：
PETROLEUM CHEMISTRY | 2015年 / 55卷 / 08期
关键词：
ethane; ethylene; oxidative dehydrogenation; OXIDATIVE DEHYDROGENATION; CATALYST;
D O I：
10.1134/S0965544115080113
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A large set (60 samples) of oxide systems containing Mo, V, Ti, Zr, Fe, Ni, Co, La, Ce, Al, Si, Sb, Bi, Nb, Sn, and Pb oxides has been obtained by synthesis. It has been found that using Al(OH)(3) (instead of Al2O3) makes it possible to prepare a modified Mo system that ensures a 93-95% selectivity of ethane dehydrogenation to ethylene with a C2H6 conversion as high as 40%. These results open the possibility of purposeful and technologically easy manufacturing of molded systems containing active lattice oxygen, which is able to mediate the oxidative dehydrogenation of ethane to ethylene.
引用
收藏
页码：640 / 644
页数：5
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