Modulating H2 sorption in metal-organic frameworks via ordered functional groups

被引：10

作者：

Dau, Phuong V. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 81期

关键词：

HYDROGEN STORAGE; ADSORPTION; PORE;

D O I：

10.1039/c4cc05265j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we present the use of presynthetic and postsynthetic modification (PSM) approaches to regulate the structural organization of functional groups in the pores of isoreticular metal-organic frameworks (IRMOFs). It has been found that the structural ordering of aryl groups within the IRMOF pores results in hysteretic H-2 sorption, while the same aryl groups introduced in a disordered manner displays reversible H-2 sorption that is more typical of the IRMOF family.

引用

页码：12154 / 12157

页数：4

共 26 条

[1] Broadly hysteretic H2 adsorption in the microporous metal-organic framework Co(1,4-benzenedipyrazolate) [J].

Choi, Hye Jin ;

Dinca, Mircea ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) :7848-+

[2] Hydrogen storage in water-stable metal-organic frameworks incorporating 1,3-and 1,4-benzenedipyrazolate [J].

Choi, Hye Jin ;

Dinca, Mircea ;

Dailly, Anne ;

Long, Jeffrey R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (01) :117-123

[3] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].

Cohen, Seth M. .

CHEMICAL REVIEWS, 2012, 112 (02) :970-1000

[4] Site-selective cyclometalation of a metal-organic framework [J].

Dau, Phuong V. ;

Kim, Min ;

Cohen, Seth M. .

CHEMICAL SCIENCE, 2013, 4 (02) :601-605

[5] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

[6] Directing the Breathing Behavior of Pillared-Layered Metal Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents [J].

Henke, Sebastian ;

Schneemann, Andreas ;

Wuetscher, Annika ;

Fischer, Roland A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (22) :9464-9474

[7] Effects of Heteroatoms on Aromatic π-π Interactions: Benzene-Pyridine and Pyridine Dimer [J].

Hohenstein, Edward G. ;

Sherrill, C. David .

JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (05) :878-886

[8] Microscopic Theory of Hysteretic Hydrogen Adsorption in Nanoporous Materials [J].

Kang, Joongoo ;

Wei, Su-Huai ;

Kim, Yong-Hyun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) :1510-+

[9] Metal-Organic Framework Regioisomers Based on Bifunctional Ligands [J].

Kim, Min ;

Boissonnault, Jake A. ;

Phuong V. Dau ;

Cohen, Seth M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (51) :12193-12196

[10] Mapping of Functional Groups in Metal-Organic Frameworks [J].

Kong, Xueqian ;

Deng, Hexiang ;

Yan, Fangyong ;

Kim, Jihan ;

Swisher, Joseph A. ;

Smit, Berend ;

Yaghi, Omar M. ;

Reimer, Jeffrey A. .

SCIENCE, 2013, 341 (6148) :882-885

← 1 2 3 →