Structural variation and luminescence properties of d10 metal ions complexes from 5-Aminotetrazolate ligand

被引：7

作者：

Lin, Jian-Qiao ^{[1
]}

Xiong, Chen ^{[1
]}

Xin, Jian-Hua ^{[1
]}

Li, Min ^{[2
]}

Guo, Wei-Hua ^{[2
]}

Liu, Fen ^{[2
]}

Tong, Xiao-Lan ^{[1
,2
]}

Ge, Yin-Chong ^{[2
]}

机构：

[1] East China Inst Technol, State Key Lab Breeding Base Nucl Resources & Envi, Nanchang 330013, Jiangxi, Peoples R China

[2] East China Univ Technol, Sch Chem Biol & Mat Sci, Nanchang, Jiangxi, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2018年 / 1166卷

关键词：

5-AminoTetrazolate; d(10) coordination architectures; Topology; Fluorescence property; METAL-ORGANIC FRAMEWORKS; CADMIUM COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; CARBOXYLATE LIGANDS; PHYSICAL-PROPERTIES; TETRAZOLATE; ARCHITECTURES; NETWORKS; CLUSTER;

D O I：

10.1016/j.molstruc.2018.04.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three new d (10)complexes with 5-aminotetrazolate (5-HATZ), [Zn-2(5-ATZ)(3)(N-3)]( n) (1), {[Cd-6( 5-ATZ)(8)Cl-5](n)center dot(H2O)(4)}(n) (2), and {[Cd-12(5-ATZ)(12)Cl-8(N-3)(4)]center dot 2H(2)O)}(n)(3) have been obtained under hydrothermal conditions and structurally characterized. Single-crystal X-ray structural analyses reveal that complex 1 can be rationalized to be 3D dia topological nets with the metal Zn-II centers acting as four-connected nodes and L acting as linkers, and the Schlafli symbol is 6(6), while 2 exhibits a 3D architecture based on six crystallographically independent hexahedral coordinated Cd-II centers linked by 5-ATZ anion and Cl anion. Complex 3 also possesses a 3D network linked by 5-ATZ anion, Cl anion as well as N-3 anion. The ligand 5-ATZ anion adopts mu(1,4)-bridging coordination mode in complex 1, mu(1,2,3),mu(1,2,)(4),mu(1,2,3,4)-bridge coordination mode in complex 2, while mu(1,2,4),mu(1,2,3,4)-bridge coordination mode in complex 3. Also, the fluorescent properties of complexes 1 and 2 have been investigated. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：1 / 6

页数：6

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