Fatty acid composition and δ13C of bulk and individual fatty acids as marker for authenticating Italian PDO/PGI extra virgin olive oils by means of isotopic ratio mass spectrometry

被引:25
作者
Faberi, Angelo [1 ]
Marianella, Rosa Maria [1 ]
Fuselli, Fabio [1 ]
La Mantia, Alessandro [1 ]
Ciardiello, Felice [1 ,2 ]
Montesano, Camilla [2 ]
Mascini, Marcello [3 ]
Sergi, Manuel [3 ]
Compagnone, Dario [3 ]
机构
[1] MiPAAF, Dipartimento Ispettorato Cent Tutela Qualita & Re, Lab Cent Roma, I-00149 Rome, Italy
[2] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[3] Univ Teramo, Fac Biosci & Technol Food Agr & Environm, I-64023 Mosciano Sant Angelo, TE, Italy
来源
JOURNAL OF MASS SPECTROMETRY | 2014年 / 49卷 / 09期
关键词
extra virgin olive oil; PDO; PGI; IRMS; FAME composition; chemometric analysis; GEOGRAPHICAL ORIGIN; MULTIVARIATE-ANALYSIS; PATTERN-RECOGNITION; RAMAN-SPECTROSCOPY; CLASSIFICATION; CHEMOMETRICS; ADULTERATION; TRACEABILITY; SPECTRA; CARBON;
D O I
10.1002/jms.3399
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
European Regulation (EEC) 2568/91 has been setting the minimum requirements in order to allow labeling of oil as extra virgin. These general requirements, are based on physical-chemical and organoleptic parameters directly linked to the freshness and quality of the product. Isotope ratio mass spectrometry (IRMS) was demonstrated to be a useful tool for the discrimination of the origin of unknown samples, because the obtained data are practically independent of the cultivar employed and the production technique. In this work, the evaluation of the composition of fatty acid methyl esters (FAME) alongside with the determination of stable isotope ratio of C in bulk oils and in main FAME constituents have been investigated as a tool to improve geographical discrimination of Italian Protected Designation of Origin/Protected Geographical Indication (PDO/PGI) samples. For this purpose, authentic PDO/PGI extra virgin olive oils were sampled at oil mills and grouped into different sets according to their areas of provenience. The use of principal component analysis and partial least squares discriminant analysis multivariate analysis techniques demonstrated that discrimination of olive oil samples can be done using geographical and pedoclimatic parameters predominantly by using C-13 results of bulk and individual fatty acids. Results showed that C-13 values are a more reliable marker of origin with respect to fatty acid composition. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码:840 / 849
页数:10
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