Synthesis of new naphthostyryl derivatives via nucleophilic substitution of methylthio group with C-nucleophiles. Molecular and crystal structure of (Z)-2-{benzo[cd]indol-2(1H)-ylidene}-2-(4-phenythiazol-2-yl)acetonitrile

被引:6
|
作者
Dyachenko, V. D. [1 ]
Kashner, A. Yu. [1 ]
Samusenko, Yu. V. [2 ]
机构
[1] Shevchenko Lugansk Natl Univ, UA-91011 Lugansk, Ukraine
[2] Korolenko Poltava Natl Pedag Univ, Poltava, Ukraine
关键词
General Chemistry; Thiazole; Cyano; Nucleophilic Substitution; Yellow Powder;
D O I
10.1134/S1070363214020169
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions of 2-(methylthio)benzo[cd]indol-1-inium iodide with C-nucleophiles proceed via substitution of methylthio group to afford new naphthostyryl derivatives. The latter were used in synthesis of the Hantzsch thiazoles. Structure of (Z)-2-{benzo[cd]indol-2(1H)-ylidene}-2-(4-phenylthiazol-2-yl)acetonitrile was studied by XRD.
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页码:259 / 263
页数:5
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