Graphene on Metal Grids as the Transparent Conductive Material for Dye Sensitized Solar Cell

被引:38
作者
Dong, Pei [1 ]
Zhu, Yu [2 ,3 ,4 ]
Zhang, Jing [1 ]
Peng, Cheng [1 ]
Yan, Zheng [2 ]
Li, Lei [2 ]
Peng, Zhiwei [2 ]
Ruan, Gedeng [2 ]
Xiao, Wanyao [4 ]
Lin, Hong [5 ]
Tour, James M. [1 ,2 ,3 ]
Lou, Jun [1 ]
机构
[1] Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
[2] Rice Univ, Dept Chem, Houston, TX 77005 USA
[3] Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
[4] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[5] Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
NATURAL DYES; FILMS; CONVERSION;
D O I
10.1021/jp505735j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal grids covered by graphene were used as transparent conductive electrodes in dye sensitized solar cells. The efficiency of dye sensitized solar cells with graphene-on-Pt grids was 0.4%. Compared to the control group, in which the platinum grids were used as a transparent conductive layer, the efficiency of dye sensitized solar cells with graphene was more than 2 times better. To our knowledge, it is the most efficient dye sensitized solar cell to use a graphene-based transparent conductive electrode without a conductive oxide support such as fluorine-doped tin oxide or indium-doped tin oxide. The dye sensitized solar cell prepared by 150 degrees C as the low temperature processes, which are essential for fabricating flexible dye sensitized solar cells, was fabricated using a hybrid graphene on Ni grids transparent conductive electrode, and it exhibited an efficiency of 0.25%. The mechanical properties of the flexible hybrid transparent electrode are better than the oxide-based transparent conductive electrode in both bending and stretching tests. Therefore, the long-term stability of the flexible dye sensitized solar cells could be enhanced by using this new transparent conductive layer.
引用
收藏
页码:25863 / 25868
页数:6
相关论文
共 34 条
[1]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[2]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[3]   Intrinsic and extrinsic performance limits of graphene devices on SiO2 [J].
Chen, Jian-Hao ;
Jang, Chaun ;
Xiao, Shudong ;
Ishigami, Masa ;
Fuhrer, Michael S. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :206-209
[4]   Dye-sensitized solar cells with conversion efficiency of 11.1% [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Watanabe, Yuki ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640
[5]   Continuous and Scalable Fabrication of Transparent Conducting Carbon Nanotube Films [J].
Dan, Budhadipta ;
Irvin, Glen C. ;
Pasquali, Matteo .
ACS NANO, 2009, 3 (04) :835-843
[6]   Silver Nanowire Networks as Flexible, Transparent, Conducting Films: Extremely High DC to Optical Conductivity Ratios [J].
De, Sukanta ;
Higgins, Thomas M. ;
Lyons, Philip E. ;
Doherty, Evelyn M. ;
Nirmalraj, Peter N. ;
Blau, Werner J. ;
Boland, John J. ;
Coleman, Jonathan N. .
ACS NANO, 2009, 3 (07) :1767-1774
[7]   Transparent and conducting electrodes for organic electronics from reduced graphene oxide [J].
Eda, Goki ;
Lin, Yun-Yue ;
Miller, Steve ;
Chen, Chun-Wei ;
Su, Wei-Fang ;
Chhowalla, Manish .
APPLIED PHYSICS LETTERS, 2008, 92 (23)
[8]   Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy [J].
Fabregat-Santiago, F ;
Bisquert, J ;
Garcia-Belmonte, G ;
Boschloo, G ;
Hagfeldt, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) :117-131
[9]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534
[10]   Effect of acid treatment on carbon nanotube-based flexible transparent conducting films [J].
Geng, Hong-Zhang ;
Kim, Ki Kang ;
So, Kang Pyo ;
Lee, Young Sil ;
Chang, Youngkyu ;
Lee, Young Hee .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) :7758-+