Graphene on Metal Grids as the Transparent Conductive Material for Dye Sensitized Solar Cell

被引:36
作者
Dong, Pei [1 ]
Zhu, Yu [2 ,3 ,4 ]
Zhang, Jing [1 ]
Peng, Cheng [1 ]
Yan, Zheng [2 ]
Li, Lei [2 ]
Peng, Zhiwei [2 ]
Ruan, Gedeng [2 ]
Xiao, Wanyao [4 ]
Lin, Hong [5 ]
Tour, James M. [1 ,2 ,3 ]
Lou, Jun [1 ]
机构
[1] Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
[2] Rice Univ, Dept Chem, Houston, TX 77005 USA
[3] Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
[4] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[5] Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
NATURAL DYES; FILMS; CONVERSION;
D O I
10.1021/jp505735j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal grids covered by graphene were used as transparent conductive electrodes in dye sensitized solar cells. The efficiency of dye sensitized solar cells with graphene-on-Pt grids was 0.4%. Compared to the control group, in which the platinum grids were used as a transparent conductive layer, the efficiency of dye sensitized solar cells with graphene was more than 2 times better. To our knowledge, it is the most efficient dye sensitized solar cell to use a graphene-based transparent conductive electrode without a conductive oxide support such as fluorine-doped tin oxide or indium-doped tin oxide. The dye sensitized solar cell prepared by 150 degrees C as the low temperature processes, which are essential for fabricating flexible dye sensitized solar cells, was fabricated using a hybrid graphene on Ni grids transparent conductive electrode, and it exhibited an efficiency of 0.25%. The mechanical properties of the flexible hybrid transparent electrode are better than the oxide-based transparent conductive electrode in both bending and stretching tests. Therefore, the long-term stability of the flexible dye sensitized solar cells could be enhanced by using this new transparent conductive layer.
引用
收藏
页码:25863 / 25868
页数:6
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