Hg2+ and Cu2+ selective detection using a dual channel receptor based on thiopyrylium scaffoldings

被引:41
作者
Abalos, Tatiana [1 ,2 ,3 ]
Jimenez, Diego [2 ]
Martinez-Manez, Ramon [1 ,2 ,3 ]
Ros-Lis, Jose Vicente [1 ]
Royo, Santiago [1 ,2 ,3 ]
Sancenon, Felix [1 ,2 ,3 ]
Soto, Juan [1 ,2 ]
Costero, Ana M. [1 ,4 ]
Gil, Salvador [1 ,4 ]
Parra, Margarita [1 ,4 ]
机构
[1] Univ Valencia, Univ Politecn Valencia, Ctr Mixto, Inst Reconocimiento Mol & Desarrollo Tecnol, E-46003 Valencia, Spain
[2] Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain
[3] Univ Valencia, CIBER BBN, E-46100 Valencia, Spain
[4] Univ Valencia, Fac Ciencias Quim, Dept Quim Organ, E-46100 Valencia, Spain
关键词
Dual channel receptor; Chromogenic Hg2+ recognition; Fluorogenic Cu2+ recognition; Thiopyrylium derivative; TRANSITION-METAL IONS; MOLECULAR INFORMATION; OPTICAL-DETECTION; MERCURY ION; ANION; RECOGNITION; SENSORS; CHEMOSENSORS; REAGENTS; SYSTEMS;
D O I
10.1016/j.tetlet.2009.04.060
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2,4,6-Triphenylthiopyrylium functionalized with an aza-oxa-thia macrocycle is able to selectively recognize Hg2+ cation by a color change and Cu2+ cation by a remarkable significant emission enhancement. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3885 / 3888
页数:4
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