Multimetallic Hierarchical Aerogels: Shape Engineering of the Building Blocks for Efficient Electrocatalysis

被引：112

作者：

Cai, Bin ^{[1
]}

Dianat, Arezoo ^{[2
,3
]}

Huebner, Rene ^{[4
]}

Liu, Wei ^{[1
]}

Wen, Dan ^{[1
]}

Benad, Albrecht ^{[1
]}

Sonntag, Luisa ^{[1
]}

Gemming, Thomas ^{[5
]}

Cuniberti, Gianaurelio ^{[2
,3
]}

Eychmueller, Alexander ^{[1
]}

机构：

[1] Tech Univ Dresden, Phys Chem, Ctr Adv Elect Dresden, Bergstr 66b, D-01062 Dresden, Germany

[2] Tech Univ Dresden, Inst Mat Sci, Hallwachsstr 3, D-01069 Dresden, Germany

[3] Tech Univ Dresden, Max Bergmann Ctr Biomat, Ctr Adv Elect Dresden, Hallwachsstr 3, D-01069 Dresden, Germany

[4] Helmholtz Zentrum Dresden Rossendorf, Bautzner Landstr 400, D-01328 Dresden, Germany

[5] IFW Dresden, Inst Complex Mat, D-01171 Dresden, Germany

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 11期

关键词：

HIGH-PERFORMANCE; OXIDIZING ETHANOL; METAL; NANOSTRUCTURES; NANOPARTICLES; NANOCRYSTALS; REPLACEMENT; OXIDATION;

D O I：

10.1002/adma.201605254

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of multimetallic hierarchical aerogels composed entirely of interconnected Ni-PdxPty nano-building-blocks with in situ engineered morphologies and compositions is demonstrated. The underlying mechanism of the galvanic shape-engineering is elucidated in terms of nanowelding of intermediate nanoparticles. The hierarchical aerogels integrate two levels of porous structures, leading to improved electrocatalysis performance.

引用

页数：9

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