Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling

被引：27

作者：

Marquez, Carlos ^{[1
]}

Cirujano, Francisco G. ^{[1
]}

Van Goethem, Cedric ^{[1
]}

Vankelecom, Ivo ^{[1
]}

De Vos, Dirk ^{[1
]}

De Baerdemaeker, Trees ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F, B-3001 Leuven, Belgium

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2018年 / 8卷 / 08期

关键词：

METAL CYANIDE CATALYSTS; HETEROGENEOUS CATALYST; EFFICIENT; ALKYNE; ALDEHYDE; LIGAND; TRIMETHYLSILYLACETYLENE; POLYMERIZATION; INDOLIZINES; CYCLIZATION;

D O I：

10.1039/c8cy00073e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

M1[Co(CN)6]2/3-type Prussian blue analogues (M1-Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14-Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu-Co PBA with the excellent selectivity obtained with Zn-Co PBA. © 2018 The Royal Society of Chemistry.

引用

页码：2061 / 2065

页数：5

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