Hydrothermal Synthesis of a New Double Perovskite-Type Bismuthate, (Ba0.75K0.14H0.11)BiO3•nH2O

被引:28
作者
Jiang, Hong [1 ]
Kumada, Nobuhiro [1 ]
Yonesaki, Yoshinori [1 ]
Takei, Takahiro [1 ]
Kinomura, Nobukazu [1 ]
Yashima, Masatorno [2 ]
Azuma, Masaki [3 ]
Oka, Kengo [3 ]
Shimakawa, Yuichi [3 ]
机构
[1] Univ Yamanashi, Grad Sch Med & Engn, Dept Res Interdisciplinary, Kofu, Yamanashi 4008511, Japan
[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Mat Sci & Engn Interdisciplinary, Yokohama, Kanagawa 2268502, Japan
[3] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
关键词
CRYSTAL-STRUCTURE; BAPB1-XBIXO3; SYSTEM; SUPERCONDUCTIVITY; DIFFRACTION; REFINEMENT;
D O I
10.1143/JJAP.48.010216
中图分类号
O59 [应用物理学];
学科分类号
摘要
A new double perovskite-type bismuthate, (Ba0.75K0.14H0.11)BiO3 center dot nH(2)O was prepared by low-temperature hydrothermal reaction. This compound had the double perovskite-type structure with a cubic cell of a = 0.85444(3) nm, in which the A site was occupied by Ba atoms, K atoms, and water molecules, and Bi atoms occupied one crystallographic site. This compound exhibited superconductive diamagnetism with an onset temperature of about 8 K. (C) 2009 The Japan Society of Applied Physics
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页数:3
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