Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal-Organic Framework

被引：17

作者：

Han, Yi ^{[1
,2
]}

Liu, Kang ^{[1
]}

Sinnwell, Michael A. ^{[2
]}

Liu, Lili ^{[2
]}

Huang, Hongliang ^{[3
]}

Thallapally, Praveen K. ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Ecochem Engn, Qingdao 266042, Shandong, Peoples R China

[2] Pacific Northwest Natl Lab, Richland, WA 99352 USA

[3] Tianjin Polytech Univ, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China

来源：

INORGANIC CHEMISTRY | 2019年 / 58卷 / 14期

关键词：

HYDROGEN STORAGE; CATION-EXCHANGE; CARBON-DIOXIDE; GAS SORPTION; CO2; BINDING; ADSORPTION; LITHIUM; PORE; ENHANCEMENT; INSERTION;

D O I：

10.1021/acs.inorgchem.9b01207

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein we report the first example of a metal-organic framework (MOF) in which the location of Li+ ions trapped in the porous confinement can be unambiguously defined by single-crystal X-ray diffraction. Furthermore, the Li+-doped MOF shows significant enhancement in gas uptake as well as selective adsorption of CO2 over CH4.

引用

页码：8922 / 8926

页数：5

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