Effect of titanium ester on synthesizing NH2-MIL-125(Ti): Morphology changes from circular plate to octahedron and rhombic dodecahedron

被引：31
作者：
Hu, Shen [1 ]
Liu, Min [1 ]
Guo, Xinwen [1 ]
Kuang, Zhichong [1 ]
Li, Keyan [1 ]
Song, Chunshan [1 ,2 ,3 ]
Zhang, Guoliang [4 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Penn State Univ, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA
[3] Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA
[4] Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou 310014, Zhejiang, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2018年 / 262卷
基金：
中国国家自然科学基金;
关键词：
MOFs; NH2-MIL-125; Morphology; METAL-ORGANIC FRAMEWORK; CRYSTAL MORPHOLOGY; SIZE; ADSORPTION; PARTICLES; ROUTES; ACID; CO2;
D O I：
10.1016/j.jssc.2018.03.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Titanium based MOF materials NH2-MIL-125 was synthesized through solvothermal method. By increasing the concentration of the reactants, the morphology of NH2-MIL-125 can be controlled from circular plate to special polyhedron. Meanwhile, the polyhedron can be modulated from octahedron to rhombic dodecahedron through changing the titanium ester of the reactants from tetraethyl titanate to tetrabutyl titanate. This is the first time to obtain NH2-MIL-125 with rhombic dodecahedron morphology. The test of acetic acid as additive on morphology changes shows that the adsorption of additives on special facets shows a more significant impact on the morphology formation. The morphology control of NH2-MIL-125 based on the modulation of the type of titanium ester, reactants concentration, and the added acetic acid concentration were detailed exhibited and explained.
引用
收藏
页码：237 / 243
页数：7
相关论文
共 35 条
  • [11] CO2 capture under humid conditions in metal-organic frameworks
    Gonzalez-Zamora, Eduardo
    Ibarra, Ilich A.
    [J]. MATERIALS CHEMISTRY FRONTIERS, 2017, 1 (08) : 1471 - 1484
  • [12] Engineering the Optical Response of the Titanium-MIL-125 Metal-Organic Framework through Ligand Functionalization
    Hendon, Christopher H.
    Tiana, Davide
    Fontecave, Marc
    Sanchez, Clement
    D'arras, Loic
    Sassoye, Capucine
    Rozes, Laurence
    Mellot-Draznieks, Caroline
    Walsh, Aron
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (30) : 10942 - 10945
  • [13] Metal-Organic Frameworks in Biomedicine
    Horcajada, Patricia
    Gref, Ruxandra
    Baati, Tarek
    Allan, Phoebe K.
    Maurin, Guillaume
    Couvreur, Patrick
    Ferey, Gerard
    Morris, Russell E.
    Serre, Christian
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1232 - 1268
  • [14] Effects of Monocarboxylic Acid Additives on Synthesizing Metal-Organic Framework NH2-MIL-125 with Controllable Size and Morphology
    Hu, Shen
    Liu, Min
    Guo, Xinwen
    Li, Keyan
    Han, Yitong
    Song, Chunshan
    Zhang, Guoliang
    [J]. CRYSTAL GROWTH & DESIGN, 2017, 17 (12) : 6586 - 6595
  • [15] Surfactant-assisted synthesis of hierarchical NH2-MIL-125 for the removal of organic dyes
    Hu, Shen
    Liu, Min
    Li, Keyan
    Song, Chunshan
    Zhang, Guoliang
    Guo, Xinwen
    [J]. RSC ADVANCES, 2017, 7 (01): : 581 - 587
  • [16] Solvothermal synthesis of NH2-MIL-125(Ti) from circular plate to octahedron
    Hu, Shen
    Liu, Min
    Li, Keyan
    Zuo, Yi
    Zhang, Anfeng
    Song, Chunshan
    Zhang, Guoliang
    Guo, Xinwen
    [J]. CRYSTENGCOMM, 2014, 16 (41): : 9645 - 9650
  • [17] Adsorption Properties of MFM-400 and MFM-401 with CO2 and Hydrocarbons: Selectivity Derived from Directed Supramolecular Interactions
    Ibarra, Ilich A.
    Mace, Amber
    Yang, Sihai
    Sun, Junliang
    Lee, Sukyung
    Chang, Jong-San
    Laaksonen, Aatto
    Schroeder, Martin
    Zou, Xiaodong
    [J]. INORGANIC CHEMISTRY, 2016, 55 (15) : 7219 - 7228
  • [18] Functional porous coordination polymers
    Kitagawa, S
    Kitaura, R
    Noro, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) : 2334 - 2375
  • [19] Metal-Organic Framework Materials as Chemical Sensors
    Kreno, Lauren E.
    Leong, Kirsty
    Farha, Omar K.
    Allendorf, Mark
    Van Duyne, Richard P.
    Hupp, Joseph T.
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1105 - 1125
  • [20] Morphological and Structural Evolutions of Metal-Organic Framework Particles from Amorphous Spheres to Crystalline Hexagonal Rods
    Lee, Hee Jung
    We, Junghun
    Kim, Jun Oh
    Kim, Dooyoung
    Cha, Wonhee
    Lee, Eunji
    Sohn, Jeungwon
    Oh, Moonhyun
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (36) : 10564 - 10568
1234