Effect of titanium ester on synthesizing NH2-MIL-125(Ti): Morphology changes from circular plate to octahedron and rhombic dodecahedron

被引：31
作者：
Hu, Shen [1 ]
Liu, Min [1 ]
Guo, Xinwen [1 ]
Kuang, Zhichong [1 ]
Li, Keyan [1 ]
Song, Chunshan [1 ,2 ,3 ]
Zhang, Guoliang [4 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Penn State Univ, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA
[3] Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA
[4] Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou 310014, Zhejiang, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2018年 / 262卷
基金：
中国国家自然科学基金;
关键词：
MOFs; NH2-MIL-125; Morphology; METAL-ORGANIC FRAMEWORK; CRYSTAL MORPHOLOGY; SIZE; ADSORPTION; PARTICLES; ROUTES; ACID; CO2;
D O I：
10.1016/j.jssc.2018.03.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Titanium based MOF materials NH2-MIL-125 was synthesized through solvothermal method. By increasing the concentration of the reactants, the morphology of NH2-MIL-125 can be controlled from circular plate to special polyhedron. Meanwhile, the polyhedron can be modulated from octahedron to rhombic dodecahedron through changing the titanium ester of the reactants from tetraethyl titanate to tetrabutyl titanate. This is the first time to obtain NH2-MIL-125 with rhombic dodecahedron morphology. The test of acetic acid as additive on morphology changes shows that the adsorption of additives on special facets shows a more significant impact on the morphology formation. The morphology control of NH2-MIL-125 based on the modulation of the type of titanium ester, reactants concentration, and the added acetic acid concentration were detailed exhibited and explained.
引用
收藏
页码：237 / 243
页数：7
相关论文
共 35 条
  • [1] Titanium coordination compounds: from discrete metal complexes to metal-organic frameworks
    Assi, Hala
    Mouchaham, Georges
    Steunou, Nathalie
    Devic, Thomas
    Serre, Christian
    [J]. CHEMICAL SOCIETY REVIEWS, 2017, 46 (11) : 3431 - 3452
  • [2] Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity
    Bohnsack, Alisha M.
    Ibarra, Ilich A.
    Bakhmutov, Vladimir I.
    Lynch, Vincent M.
    Humphrey, Simon M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (43) : 16038 - 16041
  • [3] Facile Synthesis of Highly Uniform Fe-MIL-88B Particles
    Cai, Xuechao
    Lin, Jun
    Pang, Maolin
    [J]. CRYSTAL GROWTH & DESIGN, 2016, 16 (07) : 3565 - 3568
  • [4] A study of the solvent effect on the morphology of RDX crystal by molecular modeling method
    Chen, Gang
    Xia, Mingzhu
    Lei, Wu
    Wang, Fengyun
    Gong, Xuedong
    [J]. JOURNAL OF MOLECULAR MODELING, 2013, 19 (12) : 5397 - 5406
  • [5] A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate
    Dan-Hardi, Meenakshi
    Serre, Christian
    Frot, Theo
    Rozes, Laurence
    Maurin, Guillaume
    Sanchez, Clement
    Ferey, Gerard
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) : 10857 - +
  • [6] Evidence of Photoinduced Charge Separation in the Metal-Organic Framework MIL-125(Ti)-NH2
    de Miguel, Maykel
    Ragon, Florence
    Devic, Thomas
    Serre, Christian
    Horcajada, Patricia
    Garcia, Hermenegildo
    [J]. CHEMPHYSCHEM, 2012, 13 (16) : 3651 - 3654
  • [7] Donnay JDH, 1937, AM MINERAL, V22, P446
  • [8] Titanium-Oxo Cluster Based Precise Assembly for Multidimensional Materials
    Fang, Wei-Hui
    Wang, Jian-Fang
    Zhang, Lei
    Zhang, Jian
    [J]. CHEMISTRY OF MATERIALS, 2017, 29 (07) : 2681 - 2684
  • [9] Synthetic routes toward MOF nanomorphologies
    Fluegel, Erik A.
    Ranft, Annekathrin
    Haase, Frederik
    Lotsch, Bettina V.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (20) : 10119 - 10133
  • [10] An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction
    Fu, Yanghe
    Sun, Dengrong
    Chen, Yongjuan
    Huang, Renkun
    Ding, Zhengxin
    Fu, Xianzhi
    Li, Zhaohui
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (14) : 3364 - 3367
1234