Synthesis of neodymium-doped barium nanoferrite: Analysis of structural, optical, morphological, and magnetic properties

被引:48
作者
Ahilandeswari, E. [1 ]
Kanna, R. Rajesh [2 ]
Sakthipandi, K. [1 ]
机构
[1] Sethu Inst Technol, Dept Phys, Kariapatti 626115, Tamil Nadu, India
[2] Sethu Inst Technol, Dept Elect & Commun Engn, Kariapatti 626115, Tamil Nadu, India
关键词
Nanoferrites; Structural properties; Optical properties; Dielectric properties; Magnetic properties; MICROWAVE-ABSORBING PROPERTIES; FERRITE NANOPARTICLES; DIELECTRIC-PROPERTIES; RARE-EARTH; CO; ND3+; ZN; RAMAN; SUBSTITUTION; FABRICATION;
D O I
10.1016/j.physb.2020.412425
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Neodymium (Nd3+)-doped barium nanoferrite was synthesized by sonochemical method. The cation distribution of BaFe2O4 (BFO) nanoferrite is modified by doping of Nd3+ ions with different compositions (0 <= x <= 0.1; Delta x = 0.025). Distinct changes in Raman active modes in the synthesized BaNdxFe2-xO4 nanoferrites were observed with a different composition of Nd3+ substitution. The elemental state of oxidation in the synthesized BaNdxFe2-xO4 nanoferrites was investigated. Ultraviolet diffuse reflectance spectroscopy indicated that the bandgap energy increases from 3.40 to 3.74 eV with an increase in Nd3+ concentration from 0 to 0.10. The dielectric constant values decreased with the addition of Nd3+ content. Room temperature hysteresis magnetic loop of the pure and Nd-doped BFO nanoferrites indicated that the saturation magnetization decrease with the addition of Nd3+ in BFO nanoferrites.
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页数:12
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