Carbon Dioxide Induced Phase Switching for Homogeneous-Catalyst Recycling

被引：79

作者：

Desset, Simon. L. ^{[1
]}

Cole-Hamilton, David J. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

homogeneous catalysis; hydroformylation; phase switching; rhodium; sustainable chemistry; COMPLEXES; RECOVERY; RHODIUM;

D O I：

10.1002/anie.200804729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SwitchPhos: Rhodium complexes formed from PPh3 ligands functionalized with weakly basic amidine groups are highly active catalysts for the hydroformylation of alkenes. On bubbling with CO2 in the presence of water, the yellow rhodium complexes move into the water phase, whereas bubbling with N2 at 60 °C causes them to switch back into the organic phase. The catalysts can be used for reactions in water or an organic phase. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1472 / 1474

页数：3

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