Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

被引：30

作者：

Mondal, Suvendu Sekhar ^{[1
]}

Bhunia, Asamanjoy ^{[2
]}

Demeshko, Serhiy ^{[3
]}

Kelling, Alexandra ^{[1
]}

Schilde, Uwe ^{[1
]}

Janiak, Christoph ^{[2
]}

Holdt, Hans-Juergen ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany

[2] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40204 Dusseldorf, Germany

[3] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 01期

关键词：

METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE CAPTURE; IONOTHERMAL SYNTHESIS; IONIC LIQUIDS; EXCHANGE; SOLVENT; SURFACE; LIGAND; ZINC;

D O I：

10.1039/c3ce42040j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.

引用

页码：39 / 42

页数：4

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