Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

被引：30
|
作者：
Mondal, Suvendu Sekhar [1 ]
Bhunia, Asamanjoy [2 ]
Demeshko, Serhiy [3 ]
Kelling, Alexandra [1 ]
Schilde, Uwe [1 ]
Janiak, Christoph [2 ]
Holdt, Hans-Juergen [1 ]
机构：
[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
[2] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40204 Dusseldorf, Germany
[3] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 01期
关键词：
METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE CAPTURE; IONOTHERMAL SYNTHESIS; IONIC LIQUIDS; EXCHANGE; SOLVENT; SURFACE; LIGAND; ZINC;
D O I：
10.1039/c3ce42040j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.
引用
收藏
页码：39 / 42
页数：4
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