Plasma surface modification of silica and its effect on properties of styrene-butadiene rubber compound

被引：40

作者：

Nah, C

Huh, MY

Rhee, JM

Yoon, TH

机构：

[1] Chonbuk Natl Univ, Sch Adv Mat Engn, Duckjin Gu, Chonju 561756, South Korea

[2] Kwangju Inst Sci & Technol, Dept Mat Sci & Technol, Kwangju 506712, South Korea

来源：

POLYMER INTERNATIONAL | 2002年 / 51卷 / 06期

关键词：

plasma-polymerization coating; silica; rubber compound; dispersion; physical properties;

D O I：

10.1002/pi.897

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effects of surface modification of silicas by plasma-polymerization coating, together with modification using a silane coupling agent for a comparison on the dispersion and physical properties of styrene-butadiene rubber (SBR) are reported. The chemical compositions of the plasma-polymerization coating were characterized using FTIR and Auger spectrometer and it was found that the plasma coating was composed of C=C and C-H bonds. The surface modification of silica by either plasma polymerization or silane greatly improved the dispersion of silica particles in SBR vulcanizates. The plasma-polymerization modification of silica improved the tensile modulus of SBR vulcanizates without deterioration of important basic properties such as tensile strength and elongation at break. (C) 2002 Society of Chemical Industry.

引用

页码：510 / 518

页数：9

共 30 条

[1]

ADAMSON AW, 1990, PHYSICAL CHEM SURFAC

[2] Some performance characteristics of plasma surface modified carbon black in the (SBR) matrix [J].

Akovali, G ;

Ulkem, I .

POLYMER, 1999, 40 (26) :7417-7422

[3]

Boonstra B.B., 1975, RUBBER CHEM TECHNOL, V48, P558, DOI [10.5254/1.3539660, DOI 10.5254/1.3539660]

[4]

Byers J.T, 1998, RUBBER WORLD, V218, P38

[5] Improvement of the adhesion of the resin to the metal surface by using plasma jet [J].

Chen, S ;

Ono, S ;

Teii, S ;

Yoshino, T .

SURFACE & COATINGS TECHNOLOGY, 1997, 97 (1-3) :378-384

[6]

Cunneen J.I., 1970, RUBBER CHEM TECHNOL, V43, P1215, DOI 10.5254/1.3547319

[7] EFFECT OF PLASMA POLYMERIZATION ON CARBON-FIBERS USED FOR FIBER/EPOXY COMPOSITES [J].

DILSIZ, N ;

EBERT, E ;

WEISWEILER, W ;

AKOVALI, G .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 170 (01) :241-248

[8] Reinforcement mechanisms in carbon black and silica loaded rubber melts at low stresses [J].

Eggers, H ;

Schummer, P .

RUBBER CHEMISTRY AND TECHNOLOGY, 1996, 69 (02) :253-265

[9]

Eufinger S, 1996, J APPL POLYM SCI, V61, P1503

[10] A MULTITECHNIQUE STUDY OF THE SPONTANEOUS OXIDATION OF N-HEXANE PLASMA POLYMERS [J].

GENGENBACH, TR ;

VASIC, ZR ;

CHATELIER, RC ;

GRIESSER, HJ .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (08) :1399-1414

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