Evidence of magnetoelectric coupling on calcium doped bismuth ferrite thin films grown by chemical solution deposition

被引:7
作者
Costa, L. V. [1 ]
Ranieri, M. G. [1 ]
Cilense, M. [2 ]
Longo, E. [2 ]
Simoes, A. Z. [1 ]
机构
[1] Sao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
[2] Sao Paulo State Univ, UNESP, Chem Inst Interdiciplinar Lab Ceram, Dept Phys Chem, BR-1480090 Araraquara, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
MULTIFERROIC PROPERTIES; BIFEO3; CONDUCTION; CE;
D O I
10.1063/1.4867123
中图分类号
O59 [应用物理学];
学科分类号
摘要
Magnetoelectric coupling was observed at room temperature in calcium modified bismuth ferrite BiFeO3 (BFO) thin films deposited on Pt/TiO2/SiO2/Si (100) substrates by the chemical solution deposition. Undoped and Ca-doped BiFeO3 films were coherently grown at a temperature of 500 degrees C for 2 h. The highest doped BFO film has a tetragonal structure with P4mm space group, while BFO has a rhombohedral structure with space group R3c, which can be treated as a special triclinic structure. Room temperature magnetic coercive field indicates that the undoped film is magnetically soft with maximum magnetoelectric coefficient in the longitudinal direction was about 12 V/cm. Adding Ca2+ ions to BFO in high concentration decreases the remnant polarization and stabilizes the charged domain walls which interact with oxygen vacancies reducing coercive field. (C) 2014 AIP Publishing LLC.
引用
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页数:3
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