Evidence of magnetoelectric coupling on calcium doped bismuth ferrite thin films grown by chemical solution deposition
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Costa, L. V.
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Sao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, BrazilSao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
Costa, L. V.
[1
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Ranieri, M. G.
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Sao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, BrazilSao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
Ranieri, M. G.
[1
]
Cilense, M.
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Sao Paulo State Univ, UNESP, Chem Inst Interdiciplinar Lab Ceram, Dept Phys Chem, BR-1480090 Araraquara, SP, BrazilSao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
Cilense, M.
[2
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Longo, E.
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Sao Paulo State Univ, UNESP, Chem Inst Interdiciplinar Lab Ceram, Dept Phys Chem, BR-1480090 Araraquara, SP, BrazilSao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
Longo, E.
[2
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Simoes, A. Z.
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Sao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, BrazilSao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
Simoes, A. Z.
[1
]
机构:
[1] Sao Paulo State Univ, UNESP, Engn Fac Guaratingueta, Dept Mat Sci, BR-12516410 Guaratingueta, SP, Brazil
[2] Sao Paulo State Univ, UNESP, Chem Inst Interdiciplinar Lab Ceram, Dept Phys Chem, BR-1480090 Araraquara, SP, Brazil
Magnetoelectric coupling was observed at room temperature in calcium modified bismuth ferrite BiFeO3 (BFO) thin films deposited on Pt/TiO2/SiO2/Si (100) substrates by the chemical solution deposition. Undoped and Ca-doped BiFeO3 films were coherently grown at a temperature of 500 degrees C for 2 h. The highest doped BFO film has a tetragonal structure with P4mm space group, while BFO has a rhombohedral structure with space group R3c, which can be treated as a special triclinic structure. Room temperature magnetic coercive field indicates that the undoped film is magnetically soft with maximum magnetoelectric coefficient in the longitudinal direction was about 12 V/cm. Adding Ca2+ ions to BFO in high concentration decreases the remnant polarization and stabilizes the charged domain walls which interact with oxygen vacancies reducing coercive field. (C) 2014 AIP Publishing LLC.