Hydrolysis-assisted synthesis of spherical spinel Li4Ti5O12 with advanced electrochemical performances for power lithium-ions battery

被引：7

作者：

Ge, Hao ^{[1
]}

Hao, Tingting ^{[1
]}

Tian, Hui ^{[1
]}

Song, Ying ^{[1
]}

Song, Hua ^{[2
]}

Liu, Daliang ^{[1
]}

Wu, Shuyao ^{[1
]}

Song, Xi-Ming ^{[1
]}

Lv, Li ^{[2
]}

Shi, Xicheng ^{[2
]}

机构：

[1] Liaoning Univ, Coll Chem, Liaoning Key Lab Green Synth & Preparat Chem Adv, Shenyang 110036, Peoples R China

[2] Res Inst Chem Def, Beijing 100083, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2014年 / 40卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Grain size; Spinel; Electrodes; Battery; X LESS-THAN; ANODE MATERIAL; TRANSITION; ELECTRODE;

D O I：

10.1016/j.ceramint.2014.05.139

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Spherical spinel Li4Ti5O12 with advanced electrochemical performances was synthesized via a facile hydrolysis-assisted process. The as-synthesized spherical Li4Ti5O12 exhibited narrow size distribution and high crystallinity, contributing to its excellent reversible capacity and utilization efficiency. At 0.1 C, its reversible capacity was close to the theoretical capacity of spinel Li4Ti5O12 (175 mA h g(-1)) and about 170 mA h g(-1) could be obtained in the voltage plateau (about 1.5 V). Even at 10 C, its reversible capacity could reach 150 mA h g(-1), which was higher than the reported pristine Li4Ti5O12. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：14529 / 14532

页数：4

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