Preparation and Characterization of Polyaniline/Hexagonal Boron Nitride Composites

被引:6
作者
Cakmakci, Emrah [1 ]
Madakbas, Seyfullah [1 ]
机构
[1] Marmara Univ, Dept Chem, TR-34722 Istanbul, Turkey
关键词
PANI; h-BN; thermal analysis; complexation; XRD measurements; ELECTRICAL-PROPERTIES; FUNCTIONALIZATION; POLYMERIZATION; MORPHOLOGY; NANOTUBES;
D O I
10.1515/htmp-2013-0003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyaniline (PANI) is one of the most studied conductive polymer with several unique properties and good conductivity. In this study it was aimed to prepare Polyaniline (PANI)/Hexagonal boron nitride (h-BN) composites. Chemical structures of the composites were characterized by FTIR analysis. Thermal properties of these novel composites were analyzed by TGA and DSC measurements. Glass transition temperatures and char yields of the composites increased with increasing h-BN percentage. FTIR, XRD and UV measurements indicated that the boron atoms in h-BN particles interact with the unpaired electrons in nitrogen atoms of PANI. Dielectric measurements revealed dipolar polarization behavior of the composites.
引用
收藏
页码:557 / 561
页数:5
相关论文
共 43 条
[1]   Progress in preparation, processing and applications of polyaniline [J].
Bhadra, Sambhu ;
Khastgir, Dipak ;
Singha, Nikhil K. ;
Lee, Joong Hee .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (08) :783-810
[2]   The influence of comonomers on the degradation and flammability of polyacrylonitrile: Design input for a new generation of flame retardants [J].
Crook, Vincent ;
Ebdon, John ;
Hunt, Barry ;
Joseph, Paul ;
Wyman, Paul .
POLYMER DEGRADATION AND STABILITY, 2010, 95 (12) :2260-2268
[3]   Structure and conducting properties of thermoplastic composites of polypropylene and polyaniline protonated in solid state [J].
Fryczkowski, R ;
Slusarczyk, C ;
Fabia, J .
SYNTHETIC METALS, 2006, 156 (2-4) :310-317
[4]   Synthesis and characterization of red mud/polyaniline composites:: Electrical properties and thermal stability [J].
Goek, Ayseguel ;
Omastova, Maria ;
Prokes, Jan .
EUROPEAN POLYMER JOURNAL, 2007, 43 (06) :2471-2480
[5]  
HEEGER AJ, 1995, TRENDS POLYM SCI, V3, P39
[6]   Synthesis and characterization of polyaniline-polycarbonate composites prepared by an emulsion polymerization [J].
Jeon, BH ;
Kim, S ;
Choi, MH ;
Chung, IJ .
SYNTHETIC METALS, 1999, 104 (02) :95-100
[7]   Comparative studies of chemically synthesized polyaniline and poly(o-toluidine) doped with p-toluene sulphonic acid [J].
Kulkarni, MV ;
Viswanath, AK .
EUROPEAN POLYMER JOURNAL, 2004, 40 (02) :379-384
[8]   Fabrication and characterization of well-dispersed single-walled carbon nanotube/polyaniline composites [J].
Li, XH ;
Wu, B ;
Huang, JE ;
Zhang, J ;
Liu, ZF ;
Li, HI .
CARBON, 2003, 41 (08) :1670-1673
[9]   Polyimide/montmorillonite nanocomposites with photolithographic properties [J].
Liang, ZM ;
Yin, J ;
Wu, JH ;
Qiu, ZX ;
He, FF .
EUROPEAN POLYMER JOURNAL, 2004, 40 (02) :307-314
[10]   A simple method to synthesize polyhedral hexagonal boron nitride nanofibers [J].
Lin, Liang-xu ;
Zheng, Ying ;
Li, Zhao-hui ;
shen, Xiao-nv ;
Wei, Ke-mei .
SOLID STATE SCIENCES, 2007, 9 (12) :1099-1104