Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors

被引：62

作者：

Costantini, Francesca ^{[1
]}

Bula, Wojciech P. ^{[1
]}

Salvio, Riccardo ^{[1
]}

Huskens, Jurriaan ^{[1
]}

Gardeniers, Han J. G. E. ^{[1
]}

Reinhoudt, David N. ^{[1
]}

Verboom, Willem ^{[1
]}

机构：

[1] Univ Twente, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 05期

关键词：

REACTORS;

D O I：

10.1021/ja807616z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionatized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile.

引用

页码：1650 / +

页数：3

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