Self-Healing Colloidal Crystals

被引：121
作者：
Iyer, Ashlee St. John
Lyon, L. Andrew [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 25期
关键词：
colloids; gels; polymers; self-assembly; self-healing; POLY(N-ISOPROPYLACRYLAMIDE) MICROGEL PARTICLES; POLYDISPERSE HARD-SPHERES; PHASE-BEHAVIOR; HYBRID MICROGELS; SUSPENSIONS; HYDROGEL; TEMPERATURE; CRYSTALLIZATION; NUCLEATION; MICROSCOPY;
D O I：
10.1002/anie.200901670
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Healing hands: A complex interplay between colloidal and polymeric energetics in microgel selfassembly behavior results in soft colloidal assemblies with self-healing properties. Repulsive soft spheres can adopt highly compressed conformations in colloidal crystalline lattices without directly contacting the nearest neighbors (see picture). This distant action is directly responsible for the self-healing of the assemblies. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4562 / 4566
页数：5
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