Nickel N-heterocyclic carbene-catalyzed cross-coupling reaction of aryl aldehydes with organozinc reagents to produce aryl ketones

被引：13

作者：

Jin, Cheng ^{[1
]}

Gu, Lijun ^{[2
,3
,4
]}

Yuan, Minglong ^{[4
]}

机构：

[1] New United Grp Co Ltd, Changzhou 213166, Jiangsu, Peoples R China

[2] State Ethn Affairs Commiss, Key Lab Chem Ethn Med Resources, Kunming, Peoples R China

[3] Minist Educ, Kunming, Peoples R China

[4] Yunnan Minzu Univ, Engn Res Ctr Biopolymer Funct Mat Yunnan, Kunming 650500, Yunnan, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2015年 / 5卷 / 09期

关键词：

AEROBIC OXIDATIVE CLEAVAGE; C-C BONDS; EFFICIENT SYNTHESIS; AROMATIC-ALDEHYDES; 3+2 ANNULATION; METAL-FREE; ACTIVATION; ARYLATION; STRATEGY; CONVERSION;

D O I：

10.1039/c5cy00876j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The transformation of aromatic aldehydes into aryl ketones by nickel-catalyzed cross-coupling has been developed. This transformation represents an efficient and attractive synthetic utilization of organozinc reagents. The reaction provides a mild, practical method toward the synthesis of aryl ketones which are versatile intermediates and building blocks in organic synthesis.

引用

页码：4341 / 4345

页数：5

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