Hierarchical structure and porosity in UiO-66 polyMOFs

被引：80

作者：

Ayala, Sergio, Jr. ^{[1
]}

Zhang, Zhenjie ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92023 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 21期

关键词：

METAL-ORGANIC-FRAMEWORK; FACILE SYNTHESIS; DEFECTS;

D O I：

10.1039/c6cc10225e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first polymer-MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. With appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.

引用

页码：3058 / 3061

页数：4

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