Porous ceramic supported TiO2 nanoparticles: Enhanced photocatalytic activity for Rhodamine B degradation

被引:33
作者
de Araujo Scharnberg, Allan Ramone [1 ,2 ]
de Loreto, Adrison Carvalho [2 ]
Wermuth, Tiago Bender [1 ]
Alves, Annelise Kopp [1 ]
Arcaro, Sabrina [3 ]
Mantey dos Santos, Pamela Andrea [2 ]
Lawisch Rodriguez, Adriane de Assis [2 ]
机构
[1] Fed Univ Rio Grande Sul UFRGS, Dept Mat, Lab Ceram Mat, Osvaldo Aranha 99, BR-90035190 Porto Alegre, RS, Brazil
[2] Univ Santa Cruz Do Sul, Independencia Av 2293, BR-96815900 Santa Cruz Do Sul, RS, Brazil
[3] Univ Extremo Sul Catarinense UNESC, Grad Program Mat Sci & Engn PPGCEM, Lab Tech Ceram CerTec, Av Univ 1105,POB 3167, BR-88806000 Criciuma, SC, Brazil
来源
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO | 2020年 / 59卷 / 06期
关键词
Heterogeneous photocatalysis; TiO2 nanoparticles br; Rhodamine B; Porous ceramic; DYE WASTE-WATER; PHOTODEGRADATION; OXIDATION; NANOCOMPOSITES; EFFICIENCY; TITANIA; ZNO;
D O I
10.1016/j.bsecv.2019.12.001
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Photocatalytic processes are an efficient and important technique to mineralize organic contaminants in aqueous effluents. However, it is paramount that there is a way to recover the catalyst after degradation. Based on this problem, this research seeks to evaluate the photocatalytic properties of TiO2 under porous ceramics support for the degradation of Rhodamine B (RhB). TiO2 was synthesized by sol-gel, dried at 100 degrees C and calcined at 400 degrees C. The morphological, optical and structural proprieties of the particles were characterized. The XRD patterns of samples calcined at 400 degrees C showed only the anatase phase, confirmed by Raman. Not heat-treated xerogel was amorphous. The agglomerates are composed of fine particles, in the nanometric scale of 15 nm. The bandgap of the powder is 3.21 eV, and the surface area is 60.1 m(2) g(-1). To evaluate its photocatalytic activity, the anatase TiO2 was supported in a porous ceramic substrate by a dip-coating process. The heterogeneous photocatalysis showed excellent results, with the degradation of up to 83% of RhB. It was possible obtained with successful an efficient technique for the treatment of wastewater with Anatase nanoparticles supported in the ceramic support obtained from of reuse of the residues. (C) 2019 SECV. Published by Elsevier Espana, S.L.U.
引用
收藏
页码:230 / 238
页数:9
相关论文
共 37 条
[1]  
[Anonymous], 2000, DEV MINER PROCESS, DOI DOI 10.1016/S0167-4528(00)80100E3
[2]   RAMAN-SPECTRA OF TITANIUM-DIOXIDE [J].
BALACHANDRAN, U ;
EROR, NG .
JOURNAL OF SOLID STATE CHEMISTRY, 1982, 42 (03) :276-282
[3]   Decolorizing dye wastewater from the agate industry with Fenton oxidation process [J].
Barros, AL ;
Pizzolato, TM ;
Carissimi, E ;
Schneider, IAH .
MINERALS ENGINEERING, 2006, 19 (01) :87-90
[4]  
Bordes M.C, 2007, CERAMICA VIDR, V46, P273
[5]  
Chen D., 2001, EXTERNAL INTERNAL MA
[6]   Heterogeneous photocatalysis for selective oxidation of alcohols and hydrocarbons [J].
Chen, Lang ;
Tang, Jie ;
Song, Lu-Na ;
Chen, Peng ;
He, Jie ;
Au, Chak-Tong ;
Yin, Shuang-Feng .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 242 :379-388
[7]   Synthesis of TiO2-based Photocatalysts and their Use in the Degradation of the Semi-precious-gemstone-coloring Dye Rhodamine B [J].
de Almeida, Mauricio Knak ;
Machado, Enio Leandro ;
Lopez, Diosnel Antonio R. ;
dos Santos, Pamela Andrea M. ;
Bergmann, Carlos Perez ;
Rodriguez, Adriane de Assis L. .
FME TRANSACTIONS, 2018, 46 (02) :259-265
[8]   Biosorption of rhodamine B dye from dyeing stones effluents using the green microalgae Chlorella pyrenoidosa [J].
Denardin da Rosa, Ana Lucia ;
Carissimi, Elvis ;
Dotto, Guilherme Luiz ;
Sander, Hedda ;
Feris, Liliana Amaral .
JOURNAL OF CLEANER PRODUCTION, 2018, 198 :1302-1310
[9]   Photocatalytic activity of nanocrystalline TiNb2O7 obtained by a colloidal sol-gel route [J].
Falk, G. S. ;
Borlaf, M. ;
Lopez-Munoz, M. J. ;
Rodrigues Neto, J. B. ;
Moreno, R. .
CERAMICS INTERNATIONAL, 2018, 44 (06) :7122-7127
[10]  
Lakowicz J.R., 1989, CELL STRUCT FUNCT MI, P163