Cationic guar gum orchestrated environmental synthesis for silver nano-bio-composite films (Publication with Expression of Concern)

被引:22
作者
Abdullah, Md Farooque [1 ]
Ghosh, Sumanta Kumar [2 ]
Basu, Sreyasree [1 ]
Mukherjee, Arup [1 ,2 ]
机构
[1] Univ Calcutta, Dept Chem Technol, Kolkata 700009, W Bengal, India
[2] Univ Calcutta, Ctr Res Nanosci & Nanotechnol, Kolkata 700098, India
关键词
Guar gum alkyl amine; Silver nanoparticles; Environmental synthesis; Nano-bio-composite film; LASER-ABLATION METHOD; GREEN SYNTHESIS; NANOPARTICLE RELEASE;
D O I
10.1016/j.carbpol.2015.06.029
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This work is meant for environmentally friendly synthesis and functional evaluation of silver nanoparticles in a newer cationic guar biopolymer (GGAA). Assembly of molecules in lower size range (similar to 10 nm) was attained in a biopolymer entrapped bottom-up synthesis. Guar gum is a filming biopolymer. Nanopartides encaged in cationic guar (GGAgnC) were preserved as films for months without any significant effect on particle size, distribution or plasmonic intensity. The new nano-bio-composite and films were characterized fully in FTIR, XRD, SEM and TEM studies. Silver nanoparticles induced surface water repellency remarkably and lowered moisture permeability. GGAgnC film water contact angle was recorded as 115 degrees while, that in case of GGAA was 59 degrees. GGAgnC expressed intense antimicrobial activity when tested against a range of microorganisms. Immobilized silver nanoparticles in GGAA can feasibly be used as filming microbicidals suitable for textiles, packaging and biomedical device applications. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:30 / 37
页数:8
相关论文
共 37 条
  • [1] Immobilized silver nanoparticles enhance contact killing and show highest efficacy: elucidation of the mechanism of bactericidal action of silver
    Agnihotri, Shekhar
    Mukherji, Soumyo
    Mukherji, Suparna
    [J]. NANOSCALE, 2013, 5 (16) : 7328 - 7340
  • [2] ASTM, 1995, ANN BOOK AM STAND TE
  • [3] Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent
    Cheng, Fei
    Betts, Jonathan W.
    Kelly, Stephen M.
    Schaller, Jens
    Heinze, Thomas
    [J]. GREEN CHEMISTRY, 2013, 15 (04) : 989 - 998
  • [4] Steady-shear flow of semidilute guar gum solutions with sucrose, glucose and sodium chloride at different temperatures
    Chenlo, Francisco
    Moreira, Ramon
    Silva, Claudia
    [J]. JOURNAL OF FOOD ENGINEERING, 2011, 107 (02) : 234 - 240
  • [5] Green synthesis of the silver nanoparticles mediated by pullulan and 6-carboxypullulan
    Coseri, Sergiu
    Spatareanu, Alina
    Sacarescu, Liviu
    Rimbu, Cristina
    Suteu, Daniela
    Spirk, Stefan
    Harabagiu, Valeria
    [J]. CARBOHYDRATE POLYMERS, 2015, 116 : 9 - 17
  • [6] Thermally Robust Gold and Silver Iminopyrrolidinates for Chemical Vapor Deposition of Metal Films
    Coyle, Jason P.
    Gordon, Peter G.
    Wells, Adam P.
    Mandia, David J.
    Sirianni, Eric R.
    Yap, Glenn P. A.
    Barry, Sean T.
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (22) : 4566 - 4573
  • [7] C(6)-oxidation followed by C(5)-epimerization of guar gum studied by high field NMR
    Crescenzi, V
    Dentini, M
    Risica, D
    Spadoni, S
    Skjåk-Bræk, G
    Capitani, D
    Mannina, L
    Viel, S
    [J]. BIOMACROMOLECULES, 2004, 5 (02) : 537 - 546
  • [8] Effective water disinfection using silver nanoparticle containing silica beads
    Dang Viet Quang
    Sarawade, Pradip B.
    Jeon, Sun Jeong
    Kim, Sang Hoon
    Kim, Jong-Kil
    Chai, Young Gyu
    Kim, Hee Taik
    [J]. APPLIED SURFACE SCIENCE, 2013, 266 : 280 - 287
  • [9] Biomaterial film for soluble organic sorption and anti-microbial activity in water environment
    Das, Debasis
    Mukherjee, Arup
    [J]. BIORESOURCE TECHNOLOGY, 2012, 110 : 412 - 416
  • [10] Nanoparticle release from nano-silver antimicrobial food containers
    Echegoyen, Yolanda
    Nerin, Cristina
    [J]. FOOD AND CHEMICAL TOXICOLOGY, 2013, 62 : 16 - 22