Highly efficient catalytic system for the formation of dialdehydes from dicyclopentadiene hydroformylation

被引：24

作者：

Luo, Rong ^{[1
]}

Liang, Hao-ran ^{[1
]}

Zheng, Xue-li ^{[1
]}

Fu, Hai-yan ^{[1
]}

Yuan, Mao-lin ^{[1
]}

Li, Rui-xiang ^{[1
]}

Chen, Hua ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 50卷

基金：

中国国家自然科学基金;

关键词：

Hydroformylation; Dicyclopentadiene; Rhodium complex; Mixed phosphine ligands; Tricyclodecanedialdehyde; PHOSPHINE-LIGANDS; RHODIUM; DERIVATIVES; TRIPHENYLPHOSPHINE; 4-HOMOISOTWISTANE; ALKENES;

D O I：

10.1016/j.catcom.2014.02.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rhodium-catalyzed hydroformylation of dicyclopentadiene using different kinds of mono- and bidentate phosphorus ligands was studied. The results demonstrated that the electronic and steric properties of ligand could influence the catalytic activity and the selectivity towards dialdehyde products. High conversion (99.9%) and good selectivity (95.0%) to dialdehydes were achieved under optimized reaction conditions in the presence of Rh/mixed mono- and bidentate phosphorus ligand complex (bidentate ligand: 2,2 '-bis(dipyrrolylphosphinooxy)-1,1 '-(+/-)-biphenyl (L1) and monodentate ligand: tri-(4-methoxylphenyl)phosphine (LS) (L1/L8 molar ratio 1/2)), which offers an easy approach to prepare dialdehydes from hydroformylation of cyclopentadiene under mild conditions (5.0 MPa, 100 degrees C). (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：29 / 33

页数：5

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