Luminescent Multi-Layered Polymer Coating for the Simultaneous Detection of Oxygen Pressure and Temperature

被引:23
作者
Hyakutake, Tsuyoshi [1 ]
Taguchi, Hiroyuki [1 ]
Kato, Junji [1 ]
Nishide, Hiroyuki [1 ]
Watanabe, Masahiro [2 ]
机构
[1] Waseda Univ, Dept Appl Chem, Tokyo 1698555, Japan
[2] Univ Yamanashi, Clean Energy Res Ctr, Kofu, Yamanashi 4008510, Japan
关键词
coatings; functionalization of polymers; imaging; luminescence; sensors; SENSOR; VISUALIZATION; PROBES;
D O I
10.1002/macp.200900176
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A triple-layered luminescent polymer coating was prepared to simultaneously detect both oxygen and temperature upon the coating. The coating was composed of an oxygen and a temperature sensory layer based on platinumporphyrin (PtTFP) and ruthenium phenanthroline (Ru(phen)) dye molecule, respectively. The temperature-sensitive Ru(phen) was dispersed in gas-barrier polyvinyl alcohol as the first layer, which was further coated with a water-proofing fluorine-containing polymer. The oxygen sensory layer composed of the oxygen-sensitive PtTFP and high oxygen-permeative poly(1-trimethylsilyl-1-propyne) was coated as the third layer. The two luminescences were separately monitored: the oxygen partial pressure and temperature in the range of 0-21 kPa and of 25-120 degrees C were successfully detected.
引用
收藏
页码:1230 / 1234
页数:5
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