Effect of indium on the microstructure of the interface between Sn3.13Ag0.74CuIn solder and Cu substrate

被引:29
作者
Sebo, Pavol [1 ]
Moser, Zbigniew [2 ]
Svec, Peter [3 ]
Janickovic, Dusan [3 ]
Dobrocka, Edmund [4 ]
Gasior, Wladyslaw [2 ]
Pstrus, Janus [2 ]
机构
[1] Slovak Acad Sci, Inst Mat & Machine Mech, Bratislava 83102 3, Slovakia
[2] Polish Acad Sci, Inst Met & Mat Sci, PL-30059 Krakow, Poland
[3] Slovak Acad Sci, Inst Phys, Bratislava 84511 45, Slovakia
[4] Slovak Acad Sci, Electrotech Inst, Bratislava 84104 45, Slovakia
关键词
Lead-free solders; Copper; Interaction; X-ray scan; Phase analysis; LEAD-FREE SOLDERS; GROWTH-KINETICS; SN-AG; IDENTIFICATION; COPPER; JOINTS;
D O I
10.1016/j.jallcom.2009.02.110
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Influence of indium in Sn3.13Ag0.74Cu solder containing 4, 15, 30, 50 and 75 at.% In on the microstructure at the solder/Cu interface after wetting at 523 K for 1800 s was studied. The scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDX), standard and spatially resolved X-ray diffraction (XRD) techniques were used to determine the phases present at the solder/Cu interface. It was found that for In concentration up to 30 at.% the interface is formed by Cu(6)Sn(5) phase. For higher In content (50 and 75 at.% In) interface consists of copper rich Cu(41)Sn(11) phase. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:409 / 415
页数:7
相关论文
共 10 条
[1]   Phase identification and growth kinetics of the intermetallic compounds formed during In-49Sn/Cu soldering reactions [J].
Chuang, TH ;
Yu, CL ;
Chang, SY ;
Wang, SS .
JOURNAL OF ELECTRONIC MATERIALS, 2002, 31 (06) :640-645
[2]   Intermetallic growth kinetics for Sn-Ag, Sn-Cu, and Sn-Ag-Cu lead-free solders on Cu, Ni, and Fe-42Ni substrates [J].
Dariavach, N. ;
Callahan, P. ;
Liang, J. ;
Fournelle, R. .
JOURNAL OF ELECTRONIC MATERIALS, 2006, 35 (07) :1581-1592
[3]   Interfacial reactions between lead-free solders and common base materials [J].
Laurila, T ;
Vuorinen, V ;
Kivilahti, JK .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2005, 49 (1-2) :1-60
[4]   Effect of indium on wettability of Sn-Ag-Cu solders. Experiment vs. modeling, Part I [J].
Moser, Zbigniew ;
Sebo, Pavol ;
Gasior, Wladyslaw ;
Svec, Peter ;
Pstrus, Janusz .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2009, 33 (01) :63-68
[5]  
ROMIG AD, 1984, MICROBEAM ANAL 1984, P87
[6]  
Sebo P, 2008, KOVOVE MATER, V46, P235
[7]  
Sebo P, 2005, KOVOVE MATER, V43, P202
[8]   Characterization of the reaction process in diffusion-soldered Cu/In-48 at.% Sn/Cu joints [J].
Sommadossi, S ;
Gust, W ;
Mittemeijer, EJ .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 77 (03) :924-929
[9]   INTERMETALLIC COMPOUND LAYER FORMATION BETWEEN COPPER AND HOT-DIPPED 100IN, 50IN-50SN, 100SN, AND 63SN-37PB COATINGS [J].
VIANCO, PT ;
HLAVA, PF ;
KILGO, AC .
JOURNAL OF ELECTRONIC MATERIALS, 1994, 23 (07) :583-594
[10]  
Wojewoda J, 2006, ARCH METALL MATER, V51, P345