Synthesis and crystal structure of the bi-metallic hybrid compound {Mn4(2,2′-bipyridine)2Sb4S10}

被引：9

作者：

Anderer, Carolin ^{[1
]}

Naether, Christian ^{[1
]}

Bensch, Wolfgang ^{[1
]}

机构：

[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 46卷

关键词：

Solvothermal synthesis; Hybrid compounds; Thioantimonate; Crystal structure; MIXED-VALENT THIOANTIMONATE(III; V); TRANSITION-METAL-COMPLEXES; SOLVOTHERMAL SYNTHESIS; ANTIMONY-SULFIDE; HYDROTHERMAL SYNTHESIS; THERMAL-STABILITY; MN-2(L)SB2S5 FAMILY; MAGNETIC-PROPERTIES; STRUCTURE DIRECTOR; ANION;

D O I：

10.1016/j.inoche.2014.05.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new bi-metallic inorganic-organic hybrid compound {Mn-4(2,2'-bipyridine)(2)Sb4S10} was synthesized under solvothermal conditions. Its 2D-layered network contains distinct heterocubanes constructed by SbS3 pyramids, MnS6 and MnN2S4 octahedra. The interconnection of these units leads to a layered structure with ellipsoidal rings with pores of dimension 7.8 angstrom . 8.8 angstrom. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：335 / 339

页数：5

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