Carbon-carbon bond formation and cleavage in the dimerization of a nickelacycle

被引：23
|
作者：
Ramakrishna, TVV [1 ]
Sharp, PR [1 ]
机构：
[1] Univ Missouri, Columbia, MO 65211 USA
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 13期
关键词：
D O I：
10.1021/om0497590
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Addition of 1,12-dilithiotriphenylenediyl to L2NiCl2 (L = PEt3) gives the nickelacycle L2Ni(1,12-triphenylenediyl), which decomposes to a dimer (L2NiC36H20) containing two coupled triphenylene moieties with a new C-C bond. Thermolysis of the dimer completes the coupling, yielding a chiral tetraphenylene, while alkyne addition leads to cleavage of the newly formed C-C bond of the dimer and cycloaddition of the alkyne to the triphenylene fragment.
引用
收藏
页码：3079 / 3081
页数：3
相关论文
共 50 条
  • [1] ANTIBODY CATALYSIS OF CARBON-CARBON BOND FORMATION AND CLEAVAGE
    HILVERT, D
    ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (10) : 552 - 558
  • [2] Deacylative Carbon-Carbon Bond Cleavage of Ketone Equivalents: Applications to Radical Carbon-Carbon Bond Formation Reactions
    Matsumoto, Akira
    Nguyen, Bich-Ngoc
    Honda, Tsubasa
    Sakamoto, Ryu
    Huang, Xiao
    Sakaki, Shigeyoshi
    Maruoka, Keiji
    CHEMISTRY-AN ASIAN JOURNAL, 2021, 16 (04) : 282 - 286
  • [3] CARBON-CARBON BOND CLEAVAGE IN ORGANOBORANES
    LEVY, LA
    FISHBEIN, L
    TETRAHEDRON LETTERS, 1969, (43) : 3773 - &
  • [4] Unstrained Carbon-Carbon Bond Cleavage
    Liu, Hui
    Feng, Minghao
    Jiang, Xuefeng
    CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (12) : 3360 - 3389
  • [5] DEAMINATION OF METHYLENECYCLOPROPYLCARBINYLAMINE - FORMATION OF A VINYL CATION BY CARBON-CARBON BOND CLEAVAGE
    NISHIMURA, A
    OHTA, M
    KATO, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (05) : 1530 - +
  • [6] NOVEL CLEAVAGE OF CARBON-CARBON TRIPLE BOND
    FUJITA, H
    ICHII, T
    MURAYAMA, K
    ENDO, R
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (05) : 1581 - +
  • [7] Selective Carbon-Carbon Bond Cleavage of Cyclopropanols
    McDonald, Tyler R.
    Mills, L. Reginald
    West, Michael S.
    Rousseaux, Sophie A. L.
    CHEMICAL REVIEWS, 2021, 121 (01) : 3 - 79
  • [8] β-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon-Carbon Bond Formation
    Barrett, Anthony G. M.
    Crimmin, Mark R.
    Hill, Michael S.
    Hitchcock, Peter B.
    Lomas, Sarah L.
    Mahon, Mary F.
    Procopiou, Panayiotis A.
    Suntharalingam, Kogularamanan
    ORGANOMETALLICS, 2008, 27 (23) : 6300 - 6306
  • [9] Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage
    Kakiuchi, Fumitoshi
    Kochi, Takuya
    SYNTHESIS-STUTTGART, 2008, (19): : 3013 - 3039
  • [10] Carbon-carbon bond formation in reverse
    Zhong, Hongyu
    Morandi, Bill
    NATURE SYNTHESIS, 2022, 1 (04): : 264 - 266
12345