catena-Poly[[bis(thiocyanato-κN)-cadmium (II)]-di-μ-thiourea-κ4S:S]

被引:15
|
作者
Wang, XQ [1 ]
Yu, WT [1 ]
Xu, D [1 ]
Lu, MK [1 ]
Yuan, DR [1 ]
机构
[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
关键词
D O I
10.1107/S0108270102007631
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Cd11 ion in the title complex, [Cd(SCN)2 {SC(NH2)2}2]∞, is situated at a centre of symmetry, and is bound to two N atoms belonging to thiocyanate groups and to four S atoms of bridging thiourea ligands. The structure consists of infinite chains of slightly distorted edge-shared Cd-centred octahedra. The bridging S atoms of two thiourea ligands comprise the common edge. Some thermal properties are described.
引用
收藏
页码:M336 / M337
页数:2
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