catena-Poly[[bis(thiocyanato-κN)-cadmium (II)]-di-μ-thiourea-κ4S:S]

被引：15

作者：

Wang, XQ ^{[1
]}

Yu, WT ^{[1
]}

Xu, D ^{[1
]}

Lu, MK ^{[1
]}

Yuan, DR ^{[1
]}

机构：

[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2002年 / 58卷

关键词：

D O I：

10.1107/S0108270102007631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Cd11 ion in the title complex, [Cd(SCN)2 {SC(NH2)2}2]∞, is situated at a centre of symmetry, and is bound to two N atoms belonging to thiocyanate groups and to four S atoms of bridging thiourea ligands. The structure consists of infinite chains of slightly distorted edge-shared Cd-centred octahedra. The bridging S atoms of two thiourea ligands comprise the common edge. Some thermal properties are described.

引用

页码：M336 / M337

页数：2

共 8 条

[1] A systematic FT-Raman spectroscopic study of twelve bis-thiourea complexes, A(tu)2B2 (A = Zn, Cd, Hg; B=Cl, Br, I, SCN) [J].

Alía, JM ;

Edwards, HGM ;

Stoev, MD .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (12) :2423-2435

[2]

*BRUK AXS INC, 1997, SHELXTL VERS 5 1

[3] Structure and thermal behaviour of dichlorobis(thiourea)cadmium(II), a single-source precursor for CdS thin films [J].

Krunks, M ;

Madarasz, J ;

Hiltunen, L ;

Mannonen, R ;

Mellikov, E ;

Niinisto, L .

ACTA CHEMICA SCANDINAVICA, 1997, 51 (03) :294-301

[4]

Pauling L., 1960, NATURE CHEM BOND

[5] Thermal decomposition of cadmium thiourea coordination compounds [J].

Semenov, VN ;

Naumov, AV .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (04) :495-499

[6] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767

[7]

*SIEM AN XRAY INST, 1996, XSCANS US MAN VERS 2

[8] Tetrathioureamercury(II) tetrathiocyanatomanganate(II) [J].

Yu, WT ;

Wang, XQ ;

Xu, D ;

Lu, MK ;

Yuan, DR .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 (02) :145-146

← 1 →