Vapour-liquid equilibrium and volumetric measurements for binary mixtures of 1,3-dioxolane with isomeric chlorobutanes

被引：14

作者：

Giner, B ^{[1
]}

Reyes, A ^{[1
]}

Haro, M ^{[1
]}

Martín, S ^{[1
]}

Royo, FM ^{[1
]}

机构：

[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2004年 / 42卷 / 02期

关键词：

1,3-dioxolane; chlorobutane; isobaric vapour-liquid equilibrium;

D O I：

10.1080/00319100410001656382

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isobaric vapour-liquid equilibrium measurements for 1,3-dioxolane with isomeric chlorobutane at 40.0 and 10 1.3 kPa are reported. Activity coefficients were calculated from experimental data. The VLE measurements are thermodynamically consistent. Margules, Van Laar, Wilson, NRTL and UNIQUAC equations have been used to correlate the activity coefficients and we have obtained satisfactory results. We also present density measurements of these systems at 298.15 K.

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页码：173 / 183

页数：11

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