Effect of inhibition synergism of zinc chloride and 2-mercaptobenzoxzole on protective performance of an ecofriendly silane coating on mild steel

被引:42
作者
Alinejad, Shima [1 ]
Naderi, Reza [1 ]
Mahdavian, Mohammad [2 ]
机构
[1] Univ Tehran, Sch Met & Mat Engn, Coll Engn, POB 11155-4563, Tehran, Iran
[2] Inst Color Sci & Technol, Surface Coatings & Corros Dept, POB 16765-654, Tehran, Iran
关键词
Mild steel; Silane sol-gel coating; Corrosion inhibitor; Inhibition synergism; Surface analysis; SOL-GEL COATINGS; GALVANIZED STEEL; CORROSION PROTECTION; CLAY NANOPARTICLES; ADHESION PROMOTER; MAGNESIUM ALLOYS; M NACL; FILMS; XPS; PRETREATMENT;
D O I
10.1016/j.jiec.2016.12.024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work aims to study the impact of zinc cation and 2-mercaptobenzoxzole (MBO) on the corrosion protection of a silane sol-gel coating on mild steel. First, effectiveness of the organic and inorganic inhibitors on the corrosion of bare mild steel in a NaCl solution was shown to be linked to formation of a surface film. Using electrochemical data as well as results of surface analysis, a sharp inhibition synergism was found when an equal mole percentage of ZnCl2 and MBO was added to the NaC1 solution. Finally, electrochemical data indicated superior performance of the coating with the combination of inhibitors. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:88 / 98
页数:11
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