Photochemical synthesis, structure and spectroscopic properties of [W(CO)4(C5H10N)2CH2]

被引：7

作者：

Kociecka, Paulina ^{[1
]}

Kochel, Andrzej ^{[1
]}

Szymanska-Buzar, Teresa ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 45卷

关键词：

Tungsten; Chelating amine; Photolysis; NMR method; X-ray structure; COMPLEXES; TUNGSTEN(II); REACTIVITY; CHEMISTRY;

D O I：

10.1016/j.inoche.2014.04.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dipiperidylmethane (CH(2)dipip) coordinates to photochemically created W(CO)(4) species to give a tungsten(0) complex [W(CO)(4)(CH(2)dipip)]. The structure of the new bidentate amine complex of tungsten(0) was established by spectroscopic methods (NMR, IR, UVVis) in solution and by single-crystal X-ray diffraction studies. A preliminary experiment indicates that the tungsten complex emits light at lambda(max). 556 nm, when it is excited by lambda(max) 523 nm in the solid state at room temperature. (C) 2014 Elsevier B.V. All rights reserved.

引用

收藏

页码：105 / 107

页数：3

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