Creep compliance mapping by atomic force microscopy

被引：30

作者：

Braunsmann, Christoph ^{[1
,2
]}

Proksch, Roger ^{[3
]}

Revenko, Irene ^{[3
]}

Schaeffer, Tilman E. ^{[1
,2
]}

机构：

[1] Univ Tubingen, Inst Appl Phys, D-72076 Tubingen, Germany

[2] Univ Tubingen, LISA, D-72076 Tubingen, Germany

[3] Asylum Res, Oxford Instruments Co, Santa Barbara, CA 93117 USA

来源：

POLYMER | 2014年 / 55卷 / 01期

关键词：

Nanoindentation; Viscoelasticity; Double step loading; VISCOELASTIC PROPERTIES; NANOINDENTATION; POLYMERS; INDENTATION;

D O I：

10.1016/j.polymer.2013.11.029

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present a method for mapping the spatial distribution of viscoelastic properties of heterogeneous samples using the atomic force microscope (AFM). By applying a force step load protocol to induce time dependent sample indentations we measured the local creep compliance of the sample. The creep compliance was quantified in terms of the standard linear solid model to give maps of the instant glassy modulus, the equilibrium rubbery modulus, and the retardation time. To reduce the influence of plastic deformations, the sample was preformed with an initial preload step. Different polymer samples with a homogeneous or a heterogeneous material composition on a microscopic scale were investigated. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：219 / 225

页数：7

共 42 条

[1] MEASURING THE NANOMECHANICAL PROPERTIES AND SURFACE FORCES OF MATERIALS USING AN ATOMIC FORCE MICROSCOPE
BURNHAM, NA
COLTON, RJ
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1989, 7 (04): : 2906 - 2913
[2] Using AFM force-distance curves to study the glass-to-rubber transition of amorphous polymers and their elastic-plastic properties as a function of temperature
Cappella, B
Kaliappan, SK
Sturm, H
[J]. MACROMOLECULES, 2005, 38 (05) : 1874 - 1881
[3] Cheng L, 2000, J POLYM SCI POL PHYS, V38, P10, DOI 10.1002/(SICI)1099-0488(20000101)38:1<10::AID-POLB2>3.0.CO
[4] 2-6
[5] Practical implementation of dynamic methods for measuring atomic force microscope cantilever spring constants
Cook, S. M.
Schaeffer, T. E.
Chynoweth, K. M.
Wigton, M.
Simmonds, R. W.
Lang, K. M.
[J]. NANOTECHNOLOGY, 2006, 17 (09) : 2135 - 2145
[6] Ferry J.D., 1980, VISCOELASTIC PROPERT, V3, P672
[7] Fischer-Cripps AC, 2004, MECH ENG SERIES, P280
[8] Goulding TM, 2003, HDB ADHESIVE TECHNOL, P1024
[9] ATOMIC FORCE MICROSCOPY - GENERAL-ASPECTS AND APPLICATION TO INSULATORS
HEINZELMANN, H
MEYER, E
GRUTTER, P
HIDBER, HR
ROSENTHALER, L
GUNTHERODT, HJ
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1988, 6 (02): : 275 - 278
[10] Power-Law Stress and Creep Relaxations of Single Cells Measured by Colloidal Probe Atomic Force Microscopy
Hiratsuka, Shinichiro
Mizutani, Yusuke
Toda, Akitoshi
Fukushima, Norichika
Kawahara, Koichi
Tokumoto, Hiroshi
Okajima, Takaharu
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2009, 48 (08)

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